Estimate the equilibrium number of Frenkel defects in AgBr (rock salt structure) at 500 °C. The energy formation of the defect is 110 kJ/mol, and the entropy of formation is 6.6R. The density and molecular weight are 6.5 g/cm3 and 187.8 g/mol, respectively. Assume that the Frenkel disorder occurs on the cation sub-lattice and silver ions go into the tetrahedral sites.
Estimate the equilibrium number of Frenkel defects in AgBr (rock salt structure) at 500 °C. The energy formation of the defect is 110 kJ/mol, and the entropy of formation is 6.6R. The density and molecular weight are 6.5 g/cm3 and 187.8 g/mol, respectively. Assume that the Frenkel disorder occurs on the cation sub-lattice and silver ions go into the tetrahedral sites.
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Estimate the equilibrium number of Frenkel defects in AgBr (rock salt structure) at 500 °C. The energy formation of the defect is 110 kJ/mol, and the entropy of formation is 6.6R. The density and molecular weight are 6.5 g/cm3 and 187.8 g/mol, respectively. Assume that the Frenkel disorder occurs on the cation sub-lattice and silver ions go into the tetrahedral sites.

Transcribed Image Text:5. Estimate the equilibrium number of Frenkel defects in AgBr (rock salt structure) at 500 °C. The
energy formation of the defect is 110 kJ/mol, and the entropy of formation is 6.6R. The density
and molecular weight are 6.5 g/cm3 and 187.8 g/mol, respectively. Assume that the Frenkel
disorder occurs on the cation sub-lattice and silver ions go into the tetrahedral sites.
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