En Part II: Determination of Equilibrium ConstantThe accurate concentration of diluted Fe(NO3)3 solution:0.006 MBeakerNoVolume of KSCNVolume of dilute Fe(NO3)3Absorbancesolution16.00 mLsolution4.00 mL212.00 mL8.00 mL8.00 mL312.00 mL44.00 mL16.00 mL0.4200.5280.4926.311 Find the initial [Fe³] and [SCN1] in beakers 1-4 after these solutions havebeen mixed. Refer to the Data Table for Part II for volumes used.

Part II: Determination of Kc3. Find the initial [Fe+3] and [SCN−1] in beakers 1-4 after these…

Answered: En Part II: Determination of…

Chemistry: Matter and Change

1st Edition

ISBN:9780078746376

Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom

Publisher:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom

Chapter17: Chemical Equilibrium

Section17.1: A State Of Dynamic Balance

Problem 8SSC

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Similar questions

Which of the systems described in Exercise 13.15 give homogeneous equilibria? Which give heterogeneous equilibria?
Because carbonic acid undergoes a second ionization, the student in Exercise 12.39 is concerned that the hydrogen ion concentration she calculated is not correct. She looks up the equilibrium constant for the reaction HCO,-(aq) «=* H+(aq) + COf'(aq) Upon finding that the equilibrium constant for this reaction is 4.8 X 10“H, she decides that her answer in Exercise 12.39 is correct. Explain her reasoning. A student is simulating the carbonic acid—hydrogen carbonate equilibrium in a lake: H,CO,(aq) 5=6 H+(aq) + HCO,'(aq) K = 4.4 X 10'7She starts with 0.1000 A1 carbonic acid. W hat are the concentrations of all species at equilibrium?
In the reaction in Exercise 12.33, another trial was carried out. The reaction began with an initial concentration of N2 equal to the initial concentration of NO. Each had a concentration of 0.100 mol L-1. WTat were the equilibrium concentrations of all species? The following reaction establishes equilibrium at 2000 K: N2(g) + O2(g) ^2 NO K = 4.1 X 10~4 If the reaction began with 0.100 mol L-1 of N2 and 0.100 mol L'1 ofO2, what were the equilibrium concentrations of all species?
Again the experiment in Exercise 12.33 was redesigned. This time, 0.15 mol each of N, and O2 was injected into a 5.0-L container at 2500 K, at which the equilibrium constant is 3.6 X 10-?. What was the composition of the reaction mixture at equilibrium? l'he following reaction establishes equilibrium at 2000 K: N2(g) + O2(g) *2 2 NO K = 4.1 X IO-4 If the reaction began with 0.100 mol L-1 of N2 and 0.100 mol L-’ ofO2, what were the equilibrium concentrations of all species?
. Lead(II) chloride, PbCl2(s), dissolves in water to the extent of approximately 3.6102Mat 20 °C. Calculate Kspfor PbCl2(s), and calculate its solubility in grams per liter.
How is the strength of an acid related to the position of its ionization equilibrium? Write the equations for the dissociation (ionization) of HCI, HNO3, and HClO4in water. Since all these acids are strong acids, what does this indicate about the basicity of the Cl-, NO3, and ClO4ions? Are aqueous solutions of NaCl, NaNO3, or NaClO4basic?
. The solubility product of iron(III) hydroxide is very small: Ksp=41038at 25 °C. A classical method of analysis for unknown samples containing iron is to add NaOH or NH3. This precipitates Fe(OH)3, which can then be filtered and weighed. To demonstrate that the concentration of iron remaining in solution in such a sample is very small, calculate the solubility of Fe(OH)3in moles per liter and in grams per liter.
. Under what circumstances can we compare the solubilities of two salts by directly comparing the values of their solubility products?
Which of the systems described in Exercise 13.16 give homogeneous equilibria? Which give heterogeneous equilibria?
A small quantity of a soluble salt is placed in water. Equilibrium between dissolved and undissolved salt may or may not be attained. Explain.
The equilibrium constant for the dissociation of iodine molecules to iodine atoms I2(g) 2 I(g) is 3.76 103 at 1000 K. Suppose 0.105 mol of I2 is placed in a 12.3-L flask at 1000 K. What are the concentrations of I2 and I when the system comes to equilibrium?
Le Chteliers principle is stated (Section 12-7) as follows: If a change is imposed on a system at equilibrium, the position of the equilibrium will shift in a direction that tends to reduce that change. The systemN2(g)+3H2(g)2NH3(g) is used as an example in which the addition of nitrogen gas at equilibrium results in a decrease in H2 concentration and an increase in NH3, concentration. In the experiment the volume is assumed to be constant. On the other hand, if N2 is added to the reaction system in a container with a piston so that the pressure can be held constant, the amount o f NH3 actually could decrease, and the concentration of H2 would increase as equilibrium is reestablished. Explain how this can happen. Also, if you consider this same system at equilibrium, the addition of an inert gas. holding the pressure constant, does affect the equilibrium position. Explain why the addition of an inert gas to this system in a rigid container does not affect the equilibrium position.

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