Provide an explanation for the following observations. Show resonance structures where appropriate (you may use the any Hückel program to help answer these questions). 1) Provide an explanation for the following observations. Show resonance structures where appropriate (you may use the any Hückel program to help answer these questions). (a) The dipole moment of the molecule shown is roughly -1.9 D. Add the appropriate number electrons to the MO diagram. Use the orbital coefficients to determine the atomic charge densities. Also indicate the direction of the dipole. 0.51 -0.75 0.30 -44-α- 1.48ẞ L. 0.71 -3-α-ß -0.71 -0.82 -0.250 - W₂ = a + 0.31ẞ 0.37 0.28 0.61 -₁ = a+2.17ẞ 0.52 (b) The dipole moment of furan is smaller and opposite in direction that that for pyrrole. 10 H 0.71 D 1.81 D

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter5: Resonance
Section: Chapter Questions
Problem 26CTQ
Question
Provide an explanation for the following observations. Show resonance
structures where appropriate (you may use the any Hückel program to help
answer these questions).
1) Provide an explanation for the following observations. Show resonance
structures where appropriate (you may use the any Hückel program to help
answer these questions).
(a) The dipole moment of the molecule shown is roughly -1.9 D. Add the
appropriate number electrons to the MO diagram. Use the orbital
coefficients to determine the atomic charge densities. Also indicate the
direction of the dipole.
0.51
-0.75
0.30
-44-α- 1.48ẞ
L.
0.71
-3-α-ß
-0.71
-0.82
-0.250
-
W₂ = a + 0.31ẞ
0.37
0.28
0.61
-₁ = a+2.17ẞ
0.52
(b) The dipole moment of furan is smaller and opposite in direction that that
for pyrrole.
10
H
0.71 D
1.81 D
Transcribed Image Text:Provide an explanation for the following observations. Show resonance structures where appropriate (you may use the any Hückel program to help answer these questions). 1) Provide an explanation for the following observations. Show resonance structures where appropriate (you may use the any Hückel program to help answer these questions). (a) The dipole moment of the molecule shown is roughly -1.9 D. Add the appropriate number electrons to the MO diagram. Use the orbital coefficients to determine the atomic charge densities. Also indicate the direction of the dipole. 0.51 -0.75 0.30 -44-α- 1.48ẞ L. 0.71 -3-α-ß -0.71 -0.82 -0.250 - W₂ = a + 0.31ẞ 0.37 0.28 0.61 -₁ = a+2.17ẞ 0.52 (b) The dipole moment of furan is smaller and opposite in direction that that for pyrrole. 10 H 0.71 D 1.81 D
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