3.HСОН.Consider this compound:HOH3ClSH₁H3COf hydrogen atoms H, H, and H., select the most and least acidic. Briefly explain.

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Answered: 3. H СОН. Consider this compound: HO…

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter4: Polar Bonds, Polar Reactions

Section: Chapter Questions

Problem 28E: The following are equivalent ways of asking about the acidity of an H atom: • What is the most...

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Complete the equation for the reaction between each Lewis acid-base pair. In each equation, label which starting material is the Lewis acid and which is the Lewis base; use curved arrows to show the flow of electrons in each reaction. In doing this problem, it is essential that you show valence electrons for all atoms participating in each reaction. (a) (b) (c) (d)
For the previous four questions, label each molecule that appears in the question or your answer asstrong acid, strong base, weak acid, or weak base.
For each molecule below, draw the conjugate acid or conjugate base or both if the molecule hasboth a conjugate acid and a conjugate base (e.g., water).
The following reactions illustrate Brnsted acid-base behavior. Complete each equation. a.HI(aq)+?H3O+(aq)+I(aq) b.NH3(l)+?NH4++NH2 c.H2C2O4(aq)+H2O(l)?+HC2O4(aq) d.H2N2O2(aq)+H2O(l)H3O+(aq)+? e.?+H2O(l)H3O+(aq)+CO32(aq)
As we shall see in Chapter 19, hydrogens on a carbon adjacent to a carbonyl group are far more acidic than those not adjacent to a carbonyl group. The anion derived from acetone, for example, is more stable than is the anion derived from ethane. Account for the greater stability of the anion from acetone.
Summarize the relationship between pKa and base strength by completing the followingsentences: a. For a given base, the higher the pKa of its conjugate acid, the stronger or weaker the base. b. For a given base, the lower the pKa of its conjugate acid, the stronger or weaker the base.
Rank the following compounds according to acidity, 1 being the most acidic and 4 being the least acidic. First, list the ranking number followed by the compound letter in order from 1 to 4, and then explain your reasoning in a sentence or two.
2. Rank the following compounds in order of increasing acidity, putting the least acidic first. COOH CI I I
Which compound would be the weakest acid?
2. Which is the most acidic hydrogen in the following compound? Provide a brief explanation. H H H. H, II IV +H `H.
2. Rank the following compounds from the least acidic to most acidic, provide a brief explanation, HO. HO. H2N ON ON HN A B
a, b and c

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3. H СОН. Consider this compound: HO H3Cl SH₁ H3C Of hydrogen atoms H, H, and H., select the most and least acidic. Briefly explain.