E17E.1(a) The reaction mechanism for the decomposition of A, is thought to be A, A+A A+B - where the dissociation of A, is first order in A, and the recombination of A is second order in A; the reaction of A with B is first order in both A and B. Deduce the rate law for the rate of formation of P in two ways: (i) by assuming a pre-equilibrium between A, and A, and (ii) by assuming that the steady- state approximation can be applied to A.
E17E.1(a) The reaction mechanism for the decomposition of A, is thought to be A, A+A A+B - where the dissociation of A, is first order in A, and the recombination of A is second order in A; the reaction of A with B is first order in both A and B. Deduce the rate law for the rate of formation of P in two ways: (i) by assuming a pre-equilibrium between A, and A, and (ii) by assuming that the steady- state approximation can be applied to A.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![E17E.1(a) The reaction mechanism for the decomposition of A, is thought to
be
A,
A+A
A+B -
where the dissociation of A, is first order in A, and the recombination of A
is second order in A; the reaction of A with B is first order in both A and B.
Deduce the rate law for the rate of formation of P in two ways: (i) by assuming
a pre-equilibrium between A, and A, and (ii) by assuming that the steady-
state approximation can be applied to A.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fea860af0-a470-4c58-8105-c941838a19fa%2F2761613b-00aa-4de4-9d9d-fd37753a08a5%2Frbqe1xp.png&w=3840&q=75)
Transcribed Image Text:E17E.1(a) The reaction mechanism for the decomposition of A, is thought to
be
A,
A+A
A+B -
where the dissociation of A, is first order in A, and the recombination of A
is second order in A; the reaction of A with B is first order in both A and B.
Deduce the rate law for the rate of formation of P in two ways: (i) by assuming
a pre-equilibrium between A, and A, and (ii) by assuming that the steady-
state approximation can be applied to A.
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