The mechanism for the reaction described by rst A common NO,(g) + CO(g) → CO,(g) + NO(g) stronger cen of is suggested to be (1) 2 NO,(g) NO,(g) + NO(g) (2) NO,(g) +CO(g) NO,(g) + Co,(g) d[CO}] = k,[NO2]? %3D The experimental rate law for the production of [CO2] = ki [NO2J or dt d[NO3] = 0 ), is this a valid mechanism? i.e show dt Assuming that [NO:] is governed by a steady state ( that using elementary reactions 1 and 2, the experimental rate law can found. (Hint write out all the ways d[CO2] d[NO3] and = ? ) dt = ? that [NO3] and [CO2] are created and destroyed, dt

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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The mechanism for the reaction described by
nust. A common
d(a stronger
whch ont of
ice
prhct
NO,(g) + CO(g) → CO,(g) + NO(g)
coor
on be c
is suggested to be
(1) 2NO,(g) –→ NO,(g) + NO(g)
k1
->
k2
(2) NO,(g) + CO(g) → NO,(g) + CO,(g)
d[CO2]
k[NO2]?
%3D
The experimental rate law for the production of [CO2] = k1 [NO2J² or
dt
d[NO3]
0 ), is this a valid mechanism? i.e show
Assuming that [NO3] is governed by a steady state (
dt
that using elementary reactions 1 and 2, the experimental rate law can found. (Hint write out all the ways
d[NO3]
= ?
d[C02] = ? )
%3|
and
%3D
dt
that [NO3] and [CO2] are created and destroyed,
dt
owing clecre
cel
at 25 C
NiC
C)Cu
a062
0.62 V
0.00 V
4. 460 V
Transcribed Image Text:The mechanism for the reaction described by nust. A common d(a stronger whch ont of ice prhct NO,(g) + CO(g) → CO,(g) + NO(g) coor on be c is suggested to be (1) 2NO,(g) –→ NO,(g) + NO(g) k1 -> k2 (2) NO,(g) + CO(g) → NO,(g) + CO,(g) d[CO2] k[NO2]? %3D The experimental rate law for the production of [CO2] = k1 [NO2J² or dt d[NO3] 0 ), is this a valid mechanism? i.e show Assuming that [NO3] is governed by a steady state ( dt that using elementary reactions 1 and 2, the experimental rate law can found. (Hint write out all the ways d[NO3] = ? d[C02] = ? ) %3| and %3D dt that [NO3] and [CO2] are created and destroyed, dt owing clecre cel at 25 C NiC C)Cu a062 0.62 V 0.00 V 4. 460 V
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