The gas-phase reaction of NO2 and CO produces NO and CO2: NO2(9) + CO(g) → NO Experimental data shows second-order dependence on NO2 and ze The following is a proposed mechanism for the reaction: NO2(g) + NO2(g) NO3(g) + NO(g) NO3(g) + CO(g) → Step 1: Step 2: → NO2(g) + CO2(g) Show that the proposed mechanism is valid.

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The gas-phase reaction of NO2 and CO produces NO and CO2:
NO2(9) + CO(g) → NO(g) + CO2(g)
Experimental data shows second-order dependence on NO, and zero-order for CO.
The following is a proposed mechanism for the reaction:
NO2(g) + NO2(9) → NO3(9) + NO(9)
NO3(g) + CO(g) → NO2(g) + CO»(g)
(slow)
(fast)
Step 1:
Step 2:
Show that the proposed mechanism is valid.
Transcribed Image Text:The gas-phase reaction of NO2 and CO produces NO and CO2: NO2(9) + CO(g) → NO(g) + CO2(g) Experimental data shows second-order dependence on NO, and zero-order for CO. The following is a proposed mechanism for the reaction: NO2(g) + NO2(9) → NO3(9) + NO(9) NO3(g) + CO(g) → NO2(g) + CO»(g) (slow) (fast) Step 1: Step 2: Show that the proposed mechanism is valid.
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