Suppose the decomposition of dinitrogen monoxide proceeds by the following mechanism: elementary reaction N₂O(g) → N₂(g) + O(g) k₁ 2 N₂O(g) + O(g) → N₂(g) + O₂(g) k₂ Suppose also k₁>>k₂. That is, the first step is much faster than the second. step 1 rate constant.
Suppose the decomposition of dinitrogen monoxide proceeds by the following mechanism: elementary reaction N₂O(g) → N₂(g) + O(g) k₁ 2 N₂O(g) + O(g) → N₂(g) + O₂(g) k₂ Suppose also k₁>>k₂. That is, the first step is much faster than the second. step 1 rate constant.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Suppose the decomposition of dinitrogen monoxide proceeds by the following mechanism: elementary reaction N₂O(g) → N₂(g) + O(g) k₁ 2 N₂O(g) + O(g) → N₂(g) + O₂(g) k₂ Suppose also k₁>>k₂. That is, the first step is much faster than the second. step 1 rate constant.

Transcribed Image Text:Write the balanced
chemical equation for the
overall chemical reaction:
Write the experimentally-
observable rate law for the
overall chemical reaction.
Note: your answer should
not contain the
concentrations of any
intermediates.
Express the rate constant
k for the overall chemical
reaction in terms of K₁, K₂,
and (if necessary) the rate
constants k.₁ and k.2 for
the reverse of the two
elementary reactions in
the mechanism.
0
rate = k
k = 0

Transcribed Image Text:Suppose the decomposition of dinitrogen monoxide proceeds by the following mechanism:
step
elementary reaction
1
N₂O(g) N₂(g) + O(g)
rate constant
k₁
N₂O(g) + O(g) N₂(g) + O₂(g)
k₂
Suppose also k₁k₂. That is, the first step is much faster than the second.
2
-
-
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