is p-H₂(g) → o-H₂(g) d[o-H₂(g)] dt Show that the following mechanism is consistent with this rate law: = = k[p-H₂(g)]³/2 p-H₂(g) ¹2 H(g), k_1 H(g)+p-H₂(g) ¹30-H₂(g) + H(g). Express reaction rate constant k in terms of k₁, k-1, and k2. HINT: assume steady-state approximation for the hydrogen atoms.

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The rate law for the reaction of para-hydrogen to ortho-hydrogen
p-H₂(g) → o-H₂(g)
is
d[o-H₂(g)]
= k[p-H₂(g)]³/2
dt
Show that the following mechanism is consistent with this rate law:
p-H₂(g) ¹211(g),
H(g) + p-H₂(g) 30-H₂(g) +H(g).
Express reaction rate constant k in terms of k₁, k-1, and k2. HINT: assume steady-state
approximation for the hydrogen atoms.
Transcribed Image Text:The rate law for the reaction of para-hydrogen to ortho-hydrogen p-H₂(g) → o-H₂(g) is d[o-H₂(g)] = k[p-H₂(g)]³/2 dt Show that the following mechanism is consistent with this rate law: p-H₂(g) ¹211(g), H(g) + p-H₂(g) 30-H₂(g) +H(g). Express reaction rate constant k in terms of k₁, k-1, and k2. HINT: assume steady-state approximation for the hydrogen atoms.
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