The reaction 2 NO(8) + Cl2(8) → 2 NOCI(8) was per- formed and the following data were obtained under con- ditions of constant [Cl,]: (under conditions of constant [Cl2]) Time (a) Is the following mechanism consistent with the data? NO(8) + Cl2(8) = NOCI2(8) (fast) NOCI(8) + NO(8) → 2 NOCI(8) (slow) (b) Does the linear plot guarantee that the overall rate law is second order? (ONI/I

The reaction 2 NO(8) + Cl2(8) → 2 NOCI(8) was per- formed and the following data were obtained under con- ditions of constant [Cl,]: (under conditions of constant [Cl2]) Time (a) Is the following mechanism consistent with the data? NO(8) + Cl2(8) = NOCI2(8) (fast) NOCI(8) + NO(8) → 2 NOCI(8) (slow) (b) Does the linear plot guarantee that the overall rate law is second order? (ONI/I

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Related questions

Q: 5) The homogeneous reaction in aqueous solution DO NOT USE STEADY STATE IO3 + 81 + 6H→ 313 + 3H₂0…

A: The objective of this question is to determine the rate law for the given equations.

Q: Verify that the mechanism below is consistent with a rate law of '[N2O5]/dt = -k[N205] for the…

A: Given: The decomposition of N2O5, 2N2O5(g)→Kobs4NO2(g)+O2(g) -----(A) Rate law for the above…

Q: What is the rate law for the following mechanism in terms of the overall rate constant k? A +B Step…

A: Answer: According to the law of mass action, rate of reaction for any step will directly be…

Q: The rate of a certain reaction was studied at various temperatures. The table shows temperature…

A: Given- Table for temperature and rate constant values T (K) k (s−1) 400 0.000108 420 0.000626…

Q: The rate law for the reaction 2NO(g) + Cl,(g) - 2NOCI(g) is given by R = k[NO][C2] If the following…

Q: The time elapsed is 474 min. What is the value of the rate constant, k? In([R]/[R]o) = -0.303 [R],…

Q: 3-cher The oxidation of arsenate ion by cerium(IV) ion in aqueous solution AsO,3- + 2 Ce* + H,0 - →…

Q: 10. The rate of change in colour of iodide (yellow) can be measured as it reacts with colourless…

Q: The rate of the reaction : BrO; (aq) + 5Br (aq) + 6H* (аq) %3D ЗBr, (aq) + ЗH,0 was studied and the…

Q: For a reaction A products, sicessive half_For a reaction A→ products, successive half-lives are…

A: Step 1: Yield of Aspirin:1. Moles of salicylic acid:Molar mass of salicylic acid: 138.12 g/mol.Mass…

Q: The reactant concentration in a zero-order reaction was 0.100 M after 100 s and 4.00x10-2 Mafter 400…

Q: 2A

A: We will write the rate law expression

Q: 11) The reversible reaction AB, first order in both direction, has rate equation dx =k, (a-x)-k₂x…

A: Given thatThe initial concentration of A is=aThe initial concentration of B is=0The concentration…

Q: Determine the rate law for this reaction. (Use k for the rate constant.) Rate = Calculate the rate…

Q: what is the form of the integrated rate law which will produce a straight line if the following…

Q: Be sure to answer all parts. The reaction of peroxydisulfate ion ( S,03-) with iodide ion (I) is…

A: Rate of a reaction is proportional to the molar concentration of each of the reactants raised to…

Q: Serine (C3H703N) can be oxidized to carbon dioxide and ammonia in the presence of oxygen. The…

A: Solution

Q: The reaction of UO2* with hydrogen ion in aqueous solution 2 UO,* + 4 H* – U* + UO,+ + 2 H,O is…

Q: Sort the following elementary reactions as unimolecular (1), bimolecular (2) or termolecular (3) and…

A: Molecularity is the total number of molecules of reactant species reacting. For a general reaction…

Q: Experiment [ICI]/(mmol dm³) [H,)/(mmol dm) v(moldms) 1 1.5 1.5 3.7 x 107 2 3.0 1.5 7.4 x 10 3.0 4.5…

Question

The reaction 2 NO(8) + Cl2(8) → 2 NOCI(8) was per-
formed and the following data were obtained under con-
ditions of constant [Cl,]:
(under conditions
of constant [Cl2])
Time
(a) Is the following mechanism consistent with the data?
NO(8) + Cl2(8) = NOCI2(8) (fast)
NOCI(8) + NO(8) → 2 NOCI(8) (slow)
(b) Does the linear plot guarantee that the overall rate
law is second order?
(ONI/I

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 2 steps with 3 images

SEE SOLUTION Check out a sample Q&A here

Similar questions

What is the rate law for the following mechanism in terms of the overall rate constant k? Step 1:. A+B Step 2: B+C → D (slow) C (fast) Express your answer in terms of k and the necessary concentrations (e.g., k* [A] ^3*[D]). > View Available Hint(s) nV ΑΣφ 5E.. rate =
Give the correct stereochemistry AND regiochemistry of the major product for the reaction shown:
The gas phase decomposition of nitrogen dioxide at 383 °C NO₂(g) NO(g) + ½/0₂ (9) is second order in NO₂ with a rate constant of 0.540 M¹s¹. How much time is required for the concentration of NO₂ to drop to 4.85x10-2 M if its initial concentration is 0.385 M? S
For a reaction A products, sicessive half_For a reaction A→ products, successive half-lives are observed to be 10.0,20.0 and 40.0 min for an experiment in which the initial concentration of A=0.10M. Calculate the concentration of A(M) after 39.37 minutes. Report your answer to 4 significant fgures.
For a reaction A products, sicessive half_For a reaction A→ products, successive half-lives are observed to be 10.0,20.0 and 40.0 min for an experiment in which the initial concentration of A=0.10M. Calculate the concentration of A(M) after 39.37 minutes. Report your answer to 4 significant fgures.
Consider the following proposed reaction mechanism: (1) CIO (aq) + H,O(1)= HCIO(aq) + OH (aq) [fast] (2)I (aq) + HCIO(aq) → HIO(aq) + Cl¯(aq) [slow] (3) OH (aq) + HIO(aq) → H,O() + 10 (aq) [fast] Ignoring water, how many reaction intermediates are present? O 3 O 1 O 2
The reaction of UO,* with hydrogen ion in aqueous solution 2 UO,* + 4 H* → U** + UO2²* +2 H2O is second order in UO,* and third order overall. Complete the rate law for this reaction in the box below. Use the form k[A]™[B]"... , where 'l' is understood for m, n ... (don't enter 1) and concentrations taken to the zero power do not appear. Rate =
The following initial rate data are for the reaction of UO,* with hydrogen ion in aqueous solution: 2 UO,* + 4 H*u* + UO,2* + 2 H,0 Experiment [UO,l,, M |[н"), м Initial Rate, M s! 2.43x10-3 9.70x10 3 4.85x10-3 1.94x10-2 4.36x10-3 8.72x103 0.886 0.886 4.36x10-3 1.77 14 8.72x103 1.77 Complete the rate law for this reaction in the box below. Use the form k[A]"[B]", where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n Rate = From these data, the rate constant is м?1