5) The homogeneous reaction in aqueous solution DO NOT USE STEADY STATE IO3 + 81 + 6H→ 313 + 3H₂0 has an observed rate law of r = k[IO; ][I][H*]². a) Determine the rate law for the three mechanisms below. b) Which mechanism do you think is most likely and why? i) ii) iii) IO3 + 21 + 2H+ → 2HIO+ IO (slow) followed by fast reactions IO3 + H* KHIO3 (fast to equilibrium) I + H+ HIO3 + HI HI (fast to equilibrium) HIO+HIO2 (slow) k followed by fast reactions IO; + I +2H+ k H₂l2O3 (fast to equilibrium) H₂12O3 HIO + HIO₂ (slow) followed by fast reactions
5) The homogeneous reaction in aqueous solution DO NOT USE STEADY STATE IO3 + 81 + 6H→ 313 + 3H₂0 has an observed rate law of r = k[IO; ][I][H*]². a) Determine the rate law for the three mechanisms below. b) Which mechanism do you think is most likely and why? i) ii) iii) IO3 + 21 + 2H+ → 2HIO+ IO (slow) followed by fast reactions IO3 + H* KHIO3 (fast to equilibrium) I + H+ HIO3 + HI HI (fast to equilibrium) HIO+HIO2 (slow) k followed by fast reactions IO; + I +2H+ k H₂l2O3 (fast to equilibrium) H₂12O3 HIO + HIO₂ (slow) followed by fast reactions
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
![6) The homogeneous reaction in aqueous solution Do NOT USE STEADY STATE
IO3 +81 + 6H*→ 313 + 3H₂0
has an observed rate law of r = k[IO; ][I][H*]².
a) Determine the rate law for the three mechanisms below.
b) Which mechanism do you think is most likely and why?
i)
k2HIO+ IO (slow)
ii)
iii)
IO3 + 21 + 2H+
followed by fast reactions
ka
IO; + H+ K →→HIO3 (fast to equilibrium)
103
←
I¯ + H+
kHI (fast to equilibrium)
kc
HIO3 + HI → HIO + HIO2 (slow)
followed by fast reactions
IO; + I¯ +2H* ← ka → H₂l2O3 (fast to equilibrium)
H2l2O3 kb HIO+HIO2 (slow)
followed by fast reactions
Di locais
(d](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Faadfb7f9-0c88-4068-84aa-e612dc5261e2%2F05df8101-46e5-4b0c-acb5-a3ad97f85250%2Fqq97re_processed.jpeg&w=3840&q=75)
Transcribed Image Text:6) The homogeneous reaction in aqueous solution Do NOT USE STEADY STATE
IO3 +81 + 6H*→ 313 + 3H₂0
has an observed rate law of r = k[IO; ][I][H*]².
a) Determine the rate law for the three mechanisms below.
b) Which mechanism do you think is most likely and why?
i)
k2HIO+ IO (slow)
ii)
iii)
IO3 + 21 + 2H+
followed by fast reactions
ka
IO; + H+ K →→HIO3 (fast to equilibrium)
103
←
I¯ + H+
kHI (fast to equilibrium)
kc
HIO3 + HI → HIO + HIO2 (slow)
followed by fast reactions
IO; + I¯ +2H* ← ka → H₂l2O3 (fast to equilibrium)
H2l2O3 kb HIO+HIO2 (slow)
followed by fast reactions
Di locais
(d
Expert Solution

This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by step
Solved in 3 steps with 14 images

Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education

Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning

Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY