5) The homogeneous reaction in aqueous solution DO NOT USE STEADY STATE IO3 + 81 + 6H→ 313 + 3H₂0 has an observed rate law of r = k[IO; ][I][H*]². a) Determine the rate law for the three mechanisms below. b) Which mechanism do you think is most likely and why? i) ii) iii) IO3 + 21 + 2H+ → 2HIO+ IO (slow) followed by fast reactions IO3 + H* KHIO3 (fast to equilibrium) I + H+ HIO3 + HI HI (fast to equilibrium) HIO+HIO2 (slow) k followed by fast reactions IO; + I +2H+ k H₂l2O3 (fast to equilibrium) H₂12O3 HIO + HIO₂ (slow) followed by fast reactions
5) The homogeneous reaction in aqueous solution DO NOT USE STEADY STATE IO3 + 81 + 6H→ 313 + 3H₂0 has an observed rate law of r = k[IO; ][I][H*]². a) Determine the rate law for the three mechanisms below. b) Which mechanism do you think is most likely and why? i) ii) iii) IO3 + 21 + 2H+ → 2HIO+ IO (slow) followed by fast reactions IO3 + H* KHIO3 (fast to equilibrium) I + H+ HIO3 + HI HI (fast to equilibrium) HIO+HIO2 (slow) k followed by fast reactions IO; + I +2H+ k H₂l2O3 (fast to equilibrium) H₂12O3 HIO + HIO₂ (slow) followed by fast reactions
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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