Of the three mechanisms listed below, which mechanism agrees with the overall reaction and experimental rate law. Explain your reasoning. Overall reaction: 2NO + Cl, 2NOCI Experimentally Determined Rate Law: Rate = k[NO][CI,) Mechanism 1: NO + Cl, → NOCI, (fast) NOC, + NO → 2NOCI (slow) Mechanism 2: NO + CI, → NOCI + CI (slow) NOCI + NO NOCI, (fast) Mechanism 3: NO + Cl, → NOCI + CI (slow) Cl+ NO NOCI (fast)
Of the three mechanisms listed below, which mechanism agrees with the overall reaction and experimental rate law. Explain your reasoning. Overall reaction: 2NO + Cl, 2NOCI Experimentally Determined Rate Law: Rate = k[NO][CI,) Mechanism 1: NO + Cl, → NOCI, (fast) NOC, + NO → 2NOCI (slow) Mechanism 2: NO + CI, → NOCI + CI (slow) NOCI + NO NOCI, (fast) Mechanism 3: NO + Cl, → NOCI + CI (slow) Cl+ NO NOCI (fast)
Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section14.7: Reaction Mechanisms
Problem 14.14CYU: One possible mechanism for the decomposition of nitryl chloride, NO2CI, is What is the overall...
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![Of the three mechanisms listed below, which mechanism agrees with the overall
reaction and experimental rate law. Explain your reasoning.
Overall reaction: 2NO + Cl, 2NOCI
Experimentally Determined Rate Law: Rate = k[NO][CI,]
Mechanism 1:
NO + Cl, → NOCI, (fast)
NOCI, + NO → 2NOCI (slow)
Mechanism 2:
NO + CI, → NOCI + CI (slow)
NOCI + NO NOCI, (fast)
Mechanism 3:
NO + CI, → NOCI + CI (slow)
Cl+ NO NOCÍ (fast)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F8b2b1966-cbdc-46cc-aafa-333a90f3e9b8%2Fa28da92a-e08b-4f7f-bef0-288c436909fd%2Fhk5y7ql_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Of the three mechanisms listed below, which mechanism agrees with the overall
reaction and experimental rate law. Explain your reasoning.
Overall reaction: 2NO + Cl, 2NOCI
Experimentally Determined Rate Law: Rate = k[NO][CI,]
Mechanism 1:
NO + Cl, → NOCI, (fast)
NOCI, + NO → 2NOCI (slow)
Mechanism 2:
NO + CI, → NOCI + CI (slow)
NOCI + NO NOCI, (fast)
Mechanism 3:
NO + CI, → NOCI + CI (slow)
Cl+ NO NOCÍ (fast)
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