Suppose the formation of nitryl fluoride proceeds by the following mechanism: step elementary reaction 1 NO₂ (g) +F₂ (g) → NO₂F (g) +F (g) k₁ 2 F (g) + NO₂ (g) → NO₂F (g) k₂ Suppose also k₁ «k₂. That is, the first step is much slower than the second. Write the balanced chemical equation for the overall chemical reaction. Write the experimentally- observable rate law for the overall chemical reaction. Note: your answer should not contain the concentrations of any intermediates. rate = k rate constant

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Writing the rate law implied by a simple mechanism with an initial slow...
Suppose the formation of nitryl fluoride proceeds by the following mechanism:
elementary reaction
step
1 NO₂ (g) +F₂ (g)
2
k₁
k₂
2
F (g) + NO₂(g) → NO₂F (g)
Suppose also k₁ « k₂. That is, the first step is much slower than the second.
Write the balanced chemical
equation for the overall
chemical reaction.
Write the experimentally-
observable rate law for the
overall chemical reaction.
NO₂F (g) +F (g)
Note: your answer should not
contain the concentrations of
any intermediates.
rate constant
rate = k
0+
00
X
Ś
Transcribed Image Text:Writing the rate law implied by a simple mechanism with an initial slow... Suppose the formation of nitryl fluoride proceeds by the following mechanism: elementary reaction step 1 NO₂ (g) +F₂ (g) 2 k₁ k₂ 2 F (g) + NO₂(g) → NO₂F (g) Suppose also k₁ « k₂. That is, the first step is much slower than the second. Write the balanced chemical equation for the overall chemical reaction. Write the experimentally- observable rate law for the overall chemical reaction. NO₂F (g) +F (g) Note: your answer should not contain the concentrations of any intermediates. rate constant rate = k 0+ 00 X Ś
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