Suppose the decomposition of nitryl chloride proceeds by the following mechanism: elementary reaction rate constant NO₂Cl (g) → NO₂ (g) + Cl (g) k₁ 2 C1 (g) + NO₂Cl (g) → NO₂ (g) + Cl₂ (g) k₂ Suppose also k₁ « k₂. That is, the first step is much slower than the second. step 1 Write the balanced chemical equation for the overall chemical reaction. Write the experimentally- observable rate law for the overall chemical reaction. Note: your answer should not contain the concentrations of any intermediates. 2NO₂Cl (g) rate = k - 2NO₂ (g) + Cl₂ ローロ 8 00 X

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Suppose the decomposition of nitryl chloride proceeds by the following mechanism:
elementary reaction
NO₂C1 (g) → NO₂(g) + C1 (g)
step
1
k₁
k₂
Suppose also k₁ « k₂. That is, the first step is much slower than the second.
2 C1 (g) + NO₂Cl (g) → NO₂ (g) + Cl₂ (g)
2
Write the balanced chemical
equation for the overall
chemical reaction.
Write the experimentally-
observable rate law for the
overall chemical reaction.
Note: your answer should not
contain the concentrations of
any intermediates.
rate constant
2NO₂Cl(g) 2NO₂(g) + Cl₂
rate = k
010
X
Ś
Transcribed Image Text:Suppose the decomposition of nitryl chloride proceeds by the following mechanism: elementary reaction NO₂C1 (g) → NO₂(g) + C1 (g) step 1 k₁ k₂ Suppose also k₁ « k₂. That is, the first step is much slower than the second. 2 C1 (g) + NO₂Cl (g) → NO₂ (g) + Cl₂ (g) 2 Write the balanced chemical equation for the overall chemical reaction. Write the experimentally- observable rate law for the overall chemical reaction. Note: your answer should not contain the concentrations of any intermediates. rate constant 2NO₂Cl(g) 2NO₂(g) + Cl₂ rate = k 010 X Ś
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