1. Consider the following reaction: Mg(s) + 2HCI(aq) → MgCl2(aq) + H;(g) A piece of magnesium was dropped into 0.1 M HCl and the following data was obtained: Mass of magnesium (g) Time (s) Mass of magnesium consumed (g) 0.30 4 0.15 8 0.10 12 0.063 16 0.043 20 0.027 (a) Calculate the average rate of mass of Mg consumed per second for the first twenty second. (b) Calculate the average rate of reaction in moles of Mg consumed per second for the first eight second. (Relative atomic mass of Mg = 24.3) (c) What would happen to the concentration of H* as the reaction proceeds?

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter18: Chemical Kinetics
Section: Chapter Questions
Problem 72AP
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1.
Consider the following reaction:
Mg(s) + 2HC1(aq) → MgCl½(aq) + H2(g)
A piece of magnesium was dropped into 0.1 M HCl and the following data was obtained:
Mass of magnesium (g)
Time (s)
Mass of magnesium consumed (g)
0.30
4
0.15
8
0.10
12
0.063
16
0.043
20
0.027
(a) Calculate the average rate of mass of Mg consumed per second for the first twenty second.
(b) Calculate the average rate of reaction in moles of Mg consumed per second for the first eight second.
(Relative atomic mass of Mg = 24.3)
(c) What would happen to the concentration of H* as the reaction proceeds?
(d) What would happen to the concentration of Cl¯ as the reaction proceeds?
(e) Plot a graph showing the mass of Mg against time.
(f) If the y-axis of the graph changes to "volume of hydrogen / cm³", sketch this rate curve.
(g) What will be the effect on the reaction rate if the concentration of HCl changes from 0.1 M to 0.2 M? Explain
your answer.
Transcribed Image Text:1. Consider the following reaction: Mg(s) + 2HC1(aq) → MgCl½(aq) + H2(g) A piece of magnesium was dropped into 0.1 M HCl and the following data was obtained: Mass of magnesium (g) Time (s) Mass of magnesium consumed (g) 0.30 4 0.15 8 0.10 12 0.063 16 0.043 20 0.027 (a) Calculate the average rate of mass of Mg consumed per second for the first twenty second. (b) Calculate the average rate of reaction in moles of Mg consumed per second for the first eight second. (Relative atomic mass of Mg = 24.3) (c) What would happen to the concentration of H* as the reaction proceeds? (d) What would happen to the concentration of Cl¯ as the reaction proceeds? (e) Plot a graph showing the mass of Mg against time. (f) If the y-axis of the graph changes to "volume of hydrogen / cm³", sketch this rate curve. (g) What will be the effect on the reaction rate if the concentration of HCl changes from 0.1 M to 0.2 M? Explain your answer.
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