Consider the following reaction 2NOCI + 2NO + Cl, From the three postulated mechanisms given below show what rate law each of them gives. Mechanism 1 NOC1 NO + Cl slow Cl + NOCI NOCI, fast NOCI, + NO - 2NO + Cl, fast Overall: 2NOC1 2NO + Cl, Mechanism 2 2NOC1 A NOCI, + NO slow NOCI, NO + Cl, fast Overall: 2NOCI 2NO + Cl, Mechanism 3 NOCI E NO + Cl fast, equilibrium NOCI + Cl → NO + Cl, slow Overall: 2NOCI 2NO + Cl,
Consider the following reaction 2NOCI + 2NO + Cl, From the three postulated mechanisms given below show what rate law each of them gives. Mechanism 1 NOC1 NO + Cl slow Cl + NOCI NOCI, fast NOCI, + NO - 2NO + Cl, fast Overall: 2NOC1 2NO + Cl, Mechanism 2 2NOC1 A NOCI, + NO slow NOCI, NO + Cl, fast Overall: 2NOCI 2NO + Cl, Mechanism 3 NOCI E NO + Cl fast, equilibrium NOCI + Cl → NO + Cl, slow Overall: 2NOCI 2NO + Cl,
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![Consider the following reaction
2NOC1 2NO + Cl,
From the three postulated mechanisms given below show what rate law
each of them gives.
Mechanism 1 NOC1
NO + Cl
slow
Cl + NOC1 NOCI,
fast
NOCI, + NO
2NO + Cl,
fast
Overall: 2NOCi 2NO + Cl,
Mechanism 2 2NOC1|
NOCI, + NO
slow
NOCI, –
NO + Cl,
fast
Overall: 2NOCI
2NO + Cl2
Mechanism 3
NOC1
NO + Cl
fast, equilibrium
NOCI + Cl
→ NO + Cl
slow
Overall: 2NOCI 2NO + Cl,](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F96b52401-77ae-42e3-bef0-cdd66c230602%2Facab595d-055b-4ae8-8872-cd0397bbccc6%2Fhowwgxdi_processed.png&w=3840&q=75)
Transcribed Image Text:Consider the following reaction
2NOC1 2NO + Cl,
From the three postulated mechanisms given below show what rate law
each of them gives.
Mechanism 1 NOC1
NO + Cl
slow
Cl + NOC1 NOCI,
fast
NOCI, + NO
2NO + Cl,
fast
Overall: 2NOCi 2NO + Cl,
Mechanism 2 2NOC1|
NOCI, + NO
slow
NOCI, –
NO + Cl,
fast
Overall: 2NOCI
2NO + Cl2
Mechanism 3
NOC1
NO + Cl
fast, equilibrium
NOCI + Cl
→ NO + Cl
slow
Overall: 2NOCI 2NO + Cl,
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