### Chemical Reaction Rate Law**The reaction between chlorine monoxide and nitrogen dioxide:**\[ \text{ClO}(g) + \text{NO}_2(g) + \text{M}(g) \rightarrow \text{ClONO}_2(g) + \text{M}(g) \]This reaction produces chlorine nitrate (\( \text{ClONO}_2 \)). A third molecule (\( \text{M} \)) takes part in the reaction but remains unchanged (it appears as both a reactant and a product). The reaction is first order in \([\text{ClO}]\) and \([\text{NO}_2]\).**Question:** What is the rate law of the reaction?- \( \bigcirc \) Rate = \( k[\text{ClO}][\text{NO}_2][\text{M}] \)- \( \bigcirc \) Rate = \( k[\text{ClONO}_2] \)- \( \bullet \) Rate = \( k[\text{ClONO}_2][\text{M}] \)- \( \bigcirc \) Rate = \( k[\text{ClO}][\text{NO}_2][\text{M}]^2 \)- \( \bigcirc \) Rate = \( k[\text{ClONO}_2][\text{M}]^{1.5} \)- \( \bigcirc \) Rate = \( k[\text{ClO}][\text{NO}_2] \)**Indicate the reaction order with respect to \( \text{M} \):**- \( \bigcirc \) Zero order with respect to \( \text{M} \)- \( \bullet \) Impossible to determine the order with respect to \( \text{M} \)- \( \bigcirc \) First order with respect to \( \text{M} \)**Hint:** Knowing that the reaction is first order in both \([\text{NO}_2]\) and \([\text{ClO}]\) means that the exponent for the concentrations in the rate law for both of these reactants is 1. Because no dependence on the rate was given in the problem for \( \text{M} \), we can assume that changing \([\text{M}]\) does not affect the rate of the reaction.---**Submit Button:**-

Order with respect to reactant [ClO] = 1Order with respect to reactant [NO2] = 1Solution 1) Given conditions are,Order with respect to reactant [ClO] = 1Order with respect to reactant [NO2] = 1Order with respect to reactant means the exponent of the concentration of reactant in rate law expression.That means the exponent of concentrations of reactants is 1.Therefore,Rate = k[ClO][NO2]Since, the rate of reaction is independent of [M].Therefore,Reaction order with respect to reactant [M] is,Answer: Zero order with respect to M.Answer 1: Rate = k[ClO][NO2]Answer 2 : Zero order with respect to M.

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The reaction between chlorine monoxide and nitrogen dioxide CIO(g) + NO₂(g) + M(g) → CIONO2(g) + M(g) produces chlorine nitrate (CIONO₂). A third molecule (M) takes part in the reaction but is unchanged by it (it remains "M" as a reactant and as a product). The reaction is first order in [CIO] and [NO₂]. What is the rate law of the reaction? Rate = k[CIO][NO₂][M] O Rate = k[CIONO₂] O Rate = = K[CIONO₂][M] O Rate = k[CIO][NO₂][M]* - O Rate = k[CIONO₂][M]* O Rate = k[CIO][NO₂] Indicate the reaction order with respect to M. O Zero order with respect to M O Impossible to determine the order with respect to M O First order with respect to M Hint: Knowing that the reaction is first order in both NO2 and CIO means that the exponent for the concentrations in the rate law for both of these reactants is 1. Because no dependence on the rate was given in the problem for M, we can assume that changing [M] does not affect the rate of the reaction.

The reaction between chlorine monoxide and nitrogen dioxide CIO(g) + NO₂(g) + M(g) → CIONO2(g) + M(g) produces chlorine nitrate (CIONO₂). A third molecule (M) takes part in the reaction but is unchanged by it (it remains "M" as a reactant and as a product). The reaction is first order in [CIO] and [NO₂]. What is the rate law of the reaction? Rate = k[CIO][NO₂][M] O Rate = k[CIONO₂] O Rate = = K[CIONO₂][M] O Rate = k[CIO][NO₂][M]* - O Rate = k[CIONO₂][M]* O Rate = k[CIO][NO₂] Indicate the reaction order with respect to M. O Zero order with respect to M O Impossible to determine the order with respect to M O First order with respect to M Hint: Knowing that the reaction is first order in both NO2 and CIO means that the exponent for the concentrations in the rate law for both of these reactants is 1. Because no dependence on the rate was given in the problem for M, we can assume that changing [M] does not affect the rate of the reaction.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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