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7. The following 3-step mechanism has been proposed for the reaction of chlorine and chloroform: CI,(g)2C(g) CI(g)+ CHCI,(g)– HCI(g)+CCI,(g) CI(g)+CCI,(g)-CCI,(g) The numerical vaiues of the rate constants for these steps are kj = 4.8x10; kı-3.6x10'; k=1.3x102, k=2.7x10?. Derive the rate law and the magnitude of the effective rate constant for the overall reaction.

7. The following 3-step mechanism has been proposed for the reaction of chlorine and chloroform: CI,(g)2C(g) CI(g)+ CHCI,(g)– HCI(g)+CCI,(g) CI(g)+CCI,(g)-CCI,(g) The numerical vaiues of the rate constants for these steps are kj = 4.8x10; kı-3.6x10'; k=1.3x102, k=2.7x10?. Derive the rate law and the magnitude of the effective rate constant for the overall reaction.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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7. The following 3-step mechanism has been proposed for the reaction of chlorine and chloroform: Cl,(g)2C(g) CI(g) +CHCI,(g)-HCI(g)+CC,(g) C(g)+CCI,(g)- >CCI,(g) The numerical vaiues of the rate constants for these steps are ki = 4.8x10'; k.1=3.6x10'; k=1.3x102; ki=2.7x10?. Derive the rate law and the magnitude of the effective rate constant for the overall reaction.
Transcribed Image Text:7. The following 3-step mechanism has been proposed for the reaction of chlorine and chloroform: Cl,(g)2C(g) CI(g) +CHCI,(g)-HCI(g)+CC,(g) C(g)+CCI,(g)- >CCI,(g) The numerical vaiues of the rate constants for these steps are ki = 4.8x10'; k.1=3.6x10'; k=1.3x102; ki=2.7x10?. Derive the rate law and the magnitude of the effective rate constant for the overall reaction.
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