Give the equation for quantum yield j.rate of formation of the singlet staterate of ith decay mechanismrate of ith decay mechanismrate of removal of the singlet staterate of ith decay mechanismrate of formation of the singlet staterate of removal of the singlet staterate of ith decay mechanismStep 4 of 6Give the quantum yield ;. (Use the following as necessary: kj, k1, k2, k3, and t.)k1 + k, + k=ki3k1 + k2 + k3Recalling the relationship between the overall rate constant, k, and the mean lifetime, T, give the quantum yield D; in terms of T and Tj. (Use the following as necessary: T and T;)iStep 5 of 6(c) If T1 = 1×10-7 s, T2 = 4x10-8 s, and T3 =1x10-8 s, calculate the lifetime of the singlet state and the quantum yield for the path that has T2. (Enter an unrounded value with at least 3 digits.)1using the equation given in (b).Calculate= 7.407e-9s-1Solve for T, the lifetime of the singlet state.T =.185175X SSubmit Suppose that an excited singlet, S1, can be deactivated by three different mechanisms whose rate constants are k1, k2, and k3. The rate of decay is given by -d[S1]/dt = (k1 + k2 + k3)[S1].(a) If t is the mean lifetime, that is, the time required for [S1] to decrease to 1/e0.368 of the original value, show that (k1 + k2 + k3)T = 1.(b) The overall rate constant, k, is given by the equation below.1= k = k1 + k2 + k3 =T11++T21T3Show that the quantum yield ; is given bykjkiTiwhere i denotes the ith decay mechanism.(c) If T1 = 1×10-7S, T2 = 4×10-8s, and T3 = 1×10-8s, calculate the lifetime of the singlet state and the quantum yield for the path that has T2.Step 1 of 6(a) If T is the mean lifetime, that is, the time required for [S1] to decrease to 1/e or 0.368 of the original value, show that (k, + kɔ + k3)T = 1.Give the integrated rate law. (Use the following as necessary: k1, k2, k3, and t.)(k1 +kg +k3)ª[S1]t = [S1]o ·ee-(ki+k2+k3)tStep 2 of 6We are given the relationship between [S1]t and [S1]o, when t = T.Set this equation equal to the equation from Step 1 and solve for t = t. (Use the following as necessary: k1, k2, and k3.)(k1 + k2 + k3)T =Step 3 of 6(b) The overall rate constant, k, is given by the equation below.11= k = k1 + k2 + k3 =T11++T21T3Show that the quantum yield ; is given bykiO; ==where i denotes the ith decay mechanism.

Answered: Image /qna-images/answer/9c65419b-0278-46e1-a7e9-1454764ea40a.jpg

(c) If T, = 1x10-7 s, T, = 4x 10-8 s, and T3 = 1x10-8 s, calculate the lifetime of the singlet state and the quantum yield for the path that has T7. (Enter an unrounded value with at least 3 digits.) Calculate using the equation given in (b). = 7.407e-9 X s-1 Solve for T, the lifetime of the singlet state. T=.185175

(c) If T, = 1x10-7 s, T, = 4x 10-8 s, and T3 = 1x10-8 s, calculate the lifetime of the singlet state and the quantum yield for the path that has T7. (Enter an unrounded value with at least 3 digits.) Calculate using the equation given in (b). = 7.407e-9 X s-1 Solve for T, the lifetime of the singlet state. T=.185175

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

References Use the References to access important values if needed for this question. A local AM radio station broadcasts at an energy of 4.78 x 10 kJ/photon. ( -31 1 KHz = 10³¹) Calculate the frequency at which it is broadcasting. Frequency- KHZ Submit Answer
Particle bullet Mass (kg) 0.00190 1.67 x 10 -27 proton -27 alpha particle 6.64 x 10- Velocity (m/s) Wavelength Region 313 | 5.81 × 106 1.52 × 107
View Available Hint(s) V AEO x X IXI X.10" E = kJ Submit Previous Answers X Incorrect; Try Again; 2 attempts remaining Part C ultraviolet radiation (165 nm ) Express your answer using three significant figures. ch 74% Home End Insert Delete F10 & 4. 6 8. 9. Backspace Y U F G H J KL Ent V N M
A Be3+ ion emitts a photon with a frequency of 2.56 × 1015 Hz. If the energy of the initial state of the Be3+ ion was -2.18 × 10(-18) J, calculate the energy of the final state. Express answer in scientific notation.
What is the energy of a single photon of microwave radiation with a wavelength of 0.0618 meters? Your answer should have 3 sig figs.
Alejandra just finished making her hydrogen calibration curve. Her data is best described by the following equation: ?=−127.4ln(?)+715.23y=−127.4ln⁡(x)+715.23 If she observed a line in the helium spectrum that had a scale reading of 5.91 what wavelength, in nm, would this correspond to? in sig figs
A relativistic electron has a de Broglie wavelength of 1.25 pm1.25 pm (1 pm=10−12 m).(1 pm=10−12 m). Determine its velocity, expressed as a fraction of the speed of light ?.
3, Determine the Rydberg constant from the data. Since for n1 = 2: tad**) Equation 1 릇=-R-G)- Equation 2 4 which is of the form y - mx+ b That is, Equation 2 is of the form of a straight line, hence the Rydberg constant is the negative of the slope. Plot y 1/0 vs. x 1/ni on the graph paper provided, then determine the slope m =-R," Be sure to label the axes of the graph. As a check, compare this value of RH with the y-intercept, which should equal R,(4. To make it easy, set up a table (next page) for the data. Use meters for wavelength; the units of R, will be meter". Show your calculations in the space below:
Calculate the energy in kJ/mol of a mol of photons in the microwave region of the electromagnetic spectrum that has a frequency of 1.65 × 1011 Hz. Express answer in scientific notation.
A local FM radio station broadcasts at an energy of 6.11 x 107 -29 kJ/photon. ( 1 MHz = 106 s-¹) Calculate the frequency at which it is broadcasting. Frequency = | MHz
Calculate the kinetic energy of an electron ejected from the surface of a sample of Rubidium (binding energy = 2.26 eV (where 1 eV = 1.60218 x 10-19 J) when the metal is subjected to photons having a wavelength of 325 nm.
Calculate ⟨x⟩ and ⟨x⟩^2 for the n = 3 level of a particle in a box of length a.