Draw the major and minor product that could be formed when 1-chloro-1,3-butadiene reacts with acrylonitrile. Include any relevant stereochemical configurations. CI CN
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- cis-1-Bromo-4-tert-butylcyclohexane and trans-1-bromo-4-tert-butylcyclohexane both react with sodium ethoxide in ethanol to form 4-tert-butylcyclohexene. Explain why the cis isomer reacts much more rapidly than the trans isomer.Draw the product that could be formed when 1,3-butadiene reacts with methylpropionate. Ignore stereochemistry. OCH3 you Q CARDIANTANESelect the correct isomer of 2-bromo-4-isopropyl-1-methylcyclohexane that, when subjected to ethoxide followed by hydrogenation, would yield a single isomer of 4-isopropyl-1- methylcyclohexane.
- Which isomer of 1-bromo-3-isopropylcyclohexane reacts faster when refluxed with potassium tert-butoxide, the cis isomer or the trans isomer? Draw the structure of the expected product from the faster-reacting compound.Name (including E/Z stereochemistry) the five alkenes that can produce 3-bromo-3-methylhexane on reaction with HBr. Draw the skeletal structure of each molecule.Please don't provide handwriting solution
- 15) Ignoring stereochemistry, the 1:1 reaction of chlorine with 1,3-cyclohexadiene at 25°C in the dark and in the absence of peroxide forms which of these? C1 C1 C1 6 & 60 C1 I II III IV C1 C1Please don't provide handwriting solution4. Draw the correct structure for each of the following compounds. Indicate stereochemistry if applicable. A) 2R-bromo-3S-pentanol B) 3-methyl-2E, 4Z-hepten-1-ol 10
- Poly and B-Ryan are asked by their supervisor to synthesize (1R,3R)-1-chloro-1,3- dimethylcyclopentane. To accomplish their syntheses, Poly chooses to start from a trisubstituted alkene while B-Ryan chooses to start from a disubstituted alkene isomer. Poly's synthesis provides a mixture of isomers while B-Ryan's provides two stereoisomers. Both synthetic approaches are shown below. Me Me, Me, .CI Me HCI A B-Ryan's Synthesis Me 'CI + 75% 25% Ме Me Me Me... Me B Me C HCI A Poly's Synthesis -Me Ме 'CI 'CI + + Me.. .CI + a trace mixture ; of constitutional D Ме chloroalkane isomers Using your mechanistic knowledge of alkene reactions: (a) Explain the selectivity (regio and stereo) observed in B-Ryan's synthesis. (b) Propose a mechanism that accounts the formation of isomer C in Poly's synthesis. (c) Draw the major stereoisomer(s) formed in the "trace mixture of constitutional isomers" isolated in Poly's synthesis. 9.1-Butene reacts with borane in THF followed by hydrogen peroxide in aqueous NaOH to give A (C4H10O). Treatment of A with aqueous chromic acid or CrO3 in acetic acid gives B (C4H8O₂). Draw the structure of B. • You do not have to consider stereochemistry. • In cases where there is more than one answer, just draw one. Hot Visited Sn [F ? ChemDoodleGive IUPAC names for the following structures. If appropriate, specify relative stereochemistry. 1st structure: 1,3-dipropoxypropane 2nd structure: 1,2-epoxycyclohexane An error has been detected in your answer. Check for typos, miscalculations etc. before submitting your answer.
