Draw the major and minor product that could be formed when 1-chloro-1,3-butadiene reacts with acrylonitrile. Include any relevant stereochemical configurations. CI CN
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- cis-1-Bromo-4-tert-butylcyclohexane and trans-1-bromo-4-tert-butylcyclohexane both react with sodium ethoxide in ethanol to form 4-tert-butylcyclohexene. Explain why the cis isomer reacts much more rapidly than the trans isomer.Draw the product that could be formed when 1,3-butadiene reacts with methylpropionate. Ignore stereochemistry. OCH3 you Q CARDIANTANESelect the correct isomer of 2-bromo-4-isopropyl-1-methylcyclohexane that, when subjected to ethoxide followed by hydrogenation, would yield a single isomer of 4-isopropyl-1- methylcyclohexane.
- Two substitution products result from the reaction between 3-chloro-3-methyl-1- butene with sodium acetate (CH3COO – Na +) in acetic acid under SN1. Identify the products.Poly and B-Ryan are asked by their supervisor to synthesize (1R,3R)-1-chloro-1,3- dimethylcyclopentane. To accomplish their syntheses, Poly chooses to start from a trisubstituted alkene while B-Ryan chooses to start from a disubstituted alkene isomer. Poly's synthesis provides a mixture of isomers while B-Ryan's provides two stereoisomers. Both synthetic approaches are shown below. Me Me, Me, .CI Me HCI A B-Ryan's Synthesis Me 'CI + 75% 25% Ме Me Me Me... Me B Me C HCI A Poly's Synthesis -Me Ме 'CI 'CI + + Me.. .CI + a trace mixture ; of constitutional D Ме chloroalkane isomers Using your mechanistic knowledge of alkene reactions: (a) Explain the selectivity (regio and stereo) observed in B-Ryan's synthesis. (b) Propose a mechanism that accounts the formation of isomer C in Poly's synthesis. (c) Draw the major stereoisomer(s) formed in the "trace mixture of constitutional isomers" isolated in Poly's synthesis. 9.Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry. If the product is racemic write both isomers or write racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state 'No Reaction'
- 1-Butene reacts with borane in THF followed by hydrogen peroxide in aqueous NaOH to give A (C4H10O). Treatment of A with aqueous chromic acid or CrO3 in acetic acid gives B (C4H8O₂). Draw the structure of B. • You do not have to consider stereochemistry. • In cases where there is more than one answer, just draw one. Hot Visited Sn [F ? ChemDoodleGive IUPAC names for the following structures. If appropriate, specify relative stereochemistry. 1st structure: 1,3-dipropoxypropane 2nd structure: 1,2-epoxycyclohexane An error has been detected in your answer. Check for typos, miscalculations etc. before submitting your answer.Give the IUPAC names for the following compounds. Use the abbreviations o, m, or p (no italics) for ortho, meta, or para if you choose to use these in your name. For positively charged species, name them as aryl cations. Example: ethyl cation. Be sure to specify stereochemistry when relevant. C6H5- C6H5 C6H5 Name: H H C6H5 Name: C6H5
