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Living by Chemistry

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ISBN:9781464142314

Author:Angelica M. Stacy

Publisher:Angelica M. Stacy

ChapterU5: Fire: Energy , Thermodynamics, And Oxidation-reduction

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Problem 17RE

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Draw the molecular ion (M+) for this molecule formed in the mass spectrometer. Br: -e 4
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14. Shown below are the mass spectra (without data tables) of four molecules. (The structure of each molecule is shown on the spectrum.) Mark the [M] peak for each, and indicate the molecular weight of the molecule. Relative Intensity Relative Intensity 100 80 60 40- 20 0-mm 10 100- 80 a. 20- 115-14-5501 0-mm 10 20 b. =0 20 30 30 40 40 50 50 60 m/z 60 m/z 70 70 80 80 90 100 90 100 Relative Intensity Relative Intensity 100- 80 40 20 0 100 80 40 10 20- 15-NU-5580 15 20 25 115--555 ont 10 20 30 30 35 40 45 50 55 m/z 40 50 m/z 60 60 70 65 70 75 80 Based on the five mass spectra you have seen, describe how one might identify the [M]* peak (molecular ion peak) on the mass spectrum of an unknown compound.
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Describe the High-Resolution mass spectrometry can reveal molecular formulas.
Which of the following formulae is consistent with a molecular ion of m/z 73 in a mass spectrometry experiment? O C3H8N2 O C4H11N O C4H10O O C3H5CI
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Match the molecular ion (from electron impact mass spectrometry) with the correct compound. (Make sure to consider the isotope pattern if necessary) 1001 50 Br A 121 B 122 B NH 123 123 Mass M/e 124 124 Me C 125 125 OH НО. 126 D CI 127
Given the following mass spec data, what is the molecular formula of the compound? (Show pertinent calculations on your submitted work.) Mass Intensity 104 (M+) 19.8 105 1.09 106 0.83
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Draw the molecular ion (M*) for this molecule formed in the mass spectrometer. -e :0: