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Discussion Thinking. Consider the following nitration reaction on a heterocyclic aromatic. N. N. N. Reactant A HNO3, H₂SO4 reflux NO2 Product 1 Product 2 NO2 A. Circle the nucleophilic carbon atoms of Reactant A below. Use resonance and electron-pushing arrows to explain your answer and how it affects the reactivity of the molecule. N. 0-0 B. Draw out all sigma complex resonance forms that lead to Products 1 and 2. Which product formation (Product 1 or 2) involves a lower energy pathway and why? Product 1: Product 2: C. Based on your answers from Part A and B, which product is major?

Discussion Thinking. Consider the following nitration reaction on a heterocyclic aromatic. N. N. N. Reactant A HNO3, H₂SO4 reflux NO2 Product 1 Product 2 NO2 A. Circle the nucleophilic carbon atoms of Reactant A below. Use resonance and electron-pushing arrows to explain your answer and how it affects the reactivity of the molecule. N. 0-0 B. Draw out all sigma complex resonance forms that lead to Products 1 and 2. Which product formation (Product 1 or 2) involves a lower energy pathway and why? Product 1: Product 2: C. Based on your answers from Part A and B, which product is major?

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Discussion Thinking. Consider the following nitration reaction on a heterocyclic aromatic. N. N. N. Reactant A HNO3, H₂SO4 reflux NO2 Product 1 Product 2 NO2 A. Circle the nucleophilic carbon atoms of Reactant A below. Use resonance and electron-pushing arrows to explain your answer and how it affects the reactivity of the molecule. N. 0-0 B. Draw out all sigma complex resonance forms that lead to Products 1 and 2. Which product formation (Product 1 or 2) involves a lower energy pathway and why? Product 1: Product 2: C. Based on your answers from Part A and B, which product is major?
Transcribed Image Text:Discussion Thinking. Consider the following nitration reaction on a heterocyclic aromatic. N. N. N. Reactant A HNO3, H₂SO4 reflux NO2 Product 1 Product 2 NO2 A. Circle the nucleophilic carbon atoms of Reactant A below. Use resonance and electron-pushing arrows to explain your answer and how it affects the reactivity of the molecule. N. 0-0 B. Draw out all sigma complex resonance forms that lead to Products 1 and 2. Which product formation (Product 1 or 2) involves a lower energy pathway and why? Product 1: Product 2: C. Based on your answers from Part A and B, which product is major?
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