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- hw 7 help1. List the following alcohols in order of increasing reactivity (least reactive first) toward dehydration with concentrated sulfuric acid. a) CH,CHOHCHз b) (CH3CH2)3COH c) CH3CH2OH 2. Complete the following equations for dehydration reactions. List all the alkenes that could be formed. OH OH H* H* a) (CH;CH2),CCH3- b) ningla s bru4) Complete each reaction and name the product w (CH3)2C=CHCH3 2-methyl-2-butene HCI Br₂ H₂O/acid i) BH3 ii) H₂O₂ & base Ozone, O3
- 2) Fill in the missing Reactants, Reagents, or Products b) CH₂OH НО он он OH H2 cat Pd/C H2O Cu²+ Benedict's Reagent H2O cat HNO3 OH9. Draw the structural formulas for the product(s) of each of the reactions below. ("n" indicates "many".) | b) n cIC(CH2)6CCI + n HO(CH2)2OH → |Alcohols undergo an oxidation reaction to yield carbonyl compounds on treatment with CrO3. For example, 2-tert-butylcyclohexanol gives 2-tert-butylcyclohexanone. If axial OH groups are generally more reactive than their equatorial isomers, which do you think reacts faster, the cis isomer of 2-tert-butylcyclohexanol or the trans isomer? Explain.
- 4. Draw structural formulas for all possible monohalogenation products that might be formed in the following reactions, then assign them IUPAC names. (a) + Cl₂ light10) What is the name of the major organic product of the following reaction? CH2=CHC(CH3)3 H*, H₂O A) 2,3-dimethyl-1-butanol B) 4-methyl-2-pentanol C) 3,3-dimethyl-1-butanol D) 2,3-dimethyl-2-butanol E) 3,3-dimethyl-2-butanolCan this alcohol be synthesized selectively by hydroboration-oxidation of an alkene?
- 2. Write the major products, if any, of each of the following reactions (please draw molecular structures, not just molecular formulas).K Draw the major product of this reaction. Ignore inorganic byproducts. x H₂O* Drawing Problem 310 of 20 Drawing Atoms, Bonds and Rings Draw or tap a new bond to see s suggestions Charges Draw ethylcycloheptane in a structural condensed format. < Draw the structural condensed formula of 1-heptyne. Drawing Problem 365 of 20 Draw a terminal alkene that would lead to this product under these conditions. Question 15 of 20 Drawing H₂ Pd/C Problem 297 of 20 Atoms Bonds and Rings Provide the correct common name for the skeletal (line- bond) structure shown here. Su4) Fill in the appropriate starting materials, reagents or products in the following reactions. OH / AIC13 NO₂ Y CI / AICI,