Derive the Gibbs-Thomson relation (Equation 1) between vapor pressure and the size of aspherical nanodroplet (pictorially, assume the nanodroplet is adhered to a solid surface).Equation 1: In (P)=2yvmRTrThe following will be helpful: AP = Pin - Pext = 2 and dGin = Vin dPin; dGext =Vext dPext

Step 1: The Pressure Difference due to Curvature : For a spherical droplet of radius r, the Laplace…

Answered: Derive the Gibbs-Thomson relation…

Biochemistry

9th Edition

ISBN:9781319114671

Author:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.

Publisher:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.

Chapter1: Biochemistry: An Evolving Science

Section: Chapter Questions

Problem 1P

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Derive the Gibbs-Thomson relation (Equation 1) between vapor pressure and the size of a spherical nanodroplet (pictorially, assume the nanodroplet is adhered to a solid surface). Equation 1: In (P) = 2yvm RTr The following will be helpful: AP = Pin - Pext = 2 and dGin = Vin dPin; dGext = Vext dPext