Consider a system of two energy levels separated by an energy equal to ε1. The lowest energy level is nondegenerate, and the second energy level has a degeneracy of 4. a) Write the expression for the partition function. b) Write the expression for E. Determine the value of E in the infinite temperature limit. c) Write the expression for S. Determine the value of S in the infinite temperature limit.
Consider a system of two energy levels separated by an energy equal to ε1. The lowest energy level is nondegenerate, and the second energy level has a degeneracy of 4. a) Write the expression for the partition function. b) Write the expression for E. Determine the value of E in the infinite temperature limit. c) Write the expression for S. Determine the value of S in the infinite temperature limit.
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter17: Statistical Thermodynamics: Introduction
Section: Chapter Questions
Problem 17.41E
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Transcribed Image Text:Consider a system of two energy levels separated by an energy equal to ε1. The lowest energy
level is nondegenerate, and the second energy level has a degeneracy of 4.
a) Write the expression for the partition function.
b) Write the expression for E. Determine the value of E in the infinite temperature limit.
c) Write the expression for S. Determine the value of S in the infinite temperature limit.
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