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- Alkynes do not react directly with aqueous acid as do alkenes, but will do so in the presence of mercury(II) sulfate as a Lewis acid catalyst. The reaction occurs with Markovnikov regiochemistry, so the OH group adds to the more highly substituted carbon and the H adds to the less highly substituted carbon. The initial product of the reaction is a vinyl alcohol, also called an enol. The enol immediately rearranges to a more stable ketone via tautomerization. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions -X티 Hö: H-O -CH3 -CH3 H30*Predict the major products of this organic reaction.Give the major organic product of the following reaction. NO2 HBr CH3OH NO, OMe NON Br OMe NO2 NO, Br There is no reaction under these conditions or the correct product is not listed.
- Draw the structure(s) of the major organic product(s), including counterions, of the following reaction. HBr + NH₂When propene reacts with gaseous hydrogen bromide, HBr, two products, 1-bromopropane and 2-bromopropane are formed. The reaction is a two-step process in which the electrophilic attack occurs in the first step. Identify the electrophile in this reaction Draw a diagram showing the first step of the reaction that leads to the production of 2-bromopropane.Predict the product of the following reactions based on the reactant and catalysts given.
- What reagents are needed to carry out this reaction? CH;CH,CH2CCH PCC in methylene chloride Sia2BH and then basic hydrogen peroxide Aqueous acid and mercury sulfate MCPBA and then Swern Oxidation Question 10 What is the intermediate that forms during this reaction? CH;CH,CH,CCH O an enol an epoxide an alkoxide a carbanionGive the reduction organic products of the following organic molecules (shown below) treated by sodium borohydride (NaBH4) in aqueous acidic solution of hydrochloric acid. (1) 0 (2) OH LOHTwo substitution products result from the reaction between 3-chloro-3-methyl-1- butene with sodium acetate (CH3COO – Na +) in acetic acid under SN1. Identify the products.