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- What starting materials or reagents are best used to carry out the following reaction? .CI O HNO3, H2SO4 O C12, FeCI3 O CH3CH2CI, FeC13 O FeC13. H2S04, -78 degrees Celsius2. The AH for C2H. + H2O - CAHSOH is -44 kJ. What is the AH for this reaction? 2 CaHsOH - 2 CHa + 2 H2O 19961 mole Br CC4 2 moles H,/Pt 1 mole H2 Lindlar's cataly st 2HC1 NANH, CH3C=CH 1. disiamylborane 2. HO ,H,O2,H2O 2HBR H2SO4,HgSO4 Peroxide a. b b. C С. d. e e. f
- CH3 CH3 H3C N. H Tetracaine Tetracaine can be synthesized from benzene. The synthesis involves the following steps: 1. Benzene + CH3CI, AICI3 to form product A; 2. A + HNO3, H2SO4 to form product B; 3. B + KMNO4, H2O to form product C; 4. C + SOCI, to form product D; 5. D + HOCH2CH2N(CH3)2 to form product E; 6. E + H2, Pt to form product F; 7. F + CH3CH2CH2CHO to form product G; 8. G + NABH3CN to form Tetracaine. Draw the structures of product A and product G. You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Show the order of synthesis by drawing a reaction arrow between A and G, pointing toward the later-synthesized product.Choose the correct product for each reaction. A. B. C. D. PPh3 H PPh3 || I ။Reagents a. CeHsCHO b. NaOH, ethanol c. Pyrrolidine, cat. H* j. Brz, H* d. H2C=CHCN e. H3O* f. h. BRCH2CH=CH2 i. Na* OEt, ethanol k. K* t-Buo I. CH2(CO,Et)2 m. heat CH2CH2CN LDA g. ELOC(=0)COEt Select reagents from the table to synthesize this compound from cyclopentanone. Enter the letters of the chosen reagents, in the order that you wish to use them, without spaces or punctuation (i.e. geda).
- What are the products of the following reactions?Which reaction will not lead to aromatization? NH3, H Ph- -CH3 А. CH3 H2SO4 H3C. В. 1. NH2NH2 2. air [0] R1. -R2 С. `OMe heat D. Meo1. Fill in the boxes with the missing reagents or major organic products for the alkene reactions. a. HCl b. H2O, H2SO4 с. d. 1. ВН, 2. H2O2, NaOH е. f. CI .CI g. Cl2, H2O h. 1. Н-О, Hg(OАс)2 2. NaBH4, NaOH i. 1. O3 2. Н:0, H-02 j. OH HO.
