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- 2thank uConsider the following reaction: Na:C= N. TH. a) Complete the equilibrium by predicting the product(s). b) Draw in mechanism arrows on BOTH sides of the equilibrium. Briefly explain why the products side of the equilibrium is, or is not, favoured.21. CH3CH=CH2 – CH3CH2CH3 What reactants (and catalysts) are needed to make the reaction above occur? a. heat, pressure Ob. HCI с. Н20, Н2SO4 Od. H2, Pt
- Which reaction will not lead to aromatization? NH3, H Ph- -CH3 А. CH3 H2SO4 H3C. В. 1. NH2NH2 2. air [0] R1. -R2 С. `OMe heat D. Meo1. Fill in the boxes with the missing reagents or major organic products for the alkene reactions. a. HCl b. H2O, H2SO4 с. d. 1. ВН, 2. H2O2, NaOH е. f. CI .CI g. Cl2, H2O h. 1. Н-О, Hg(OАс)2 2. NaBH4, NaOH i. 1. O3 2. Н:0, H-02 j. OH HO.A. B. C. D. E. F. G. 1² C6H1002 NaOH/H₂O 1) R₂BH 2) H₂O2, H₂O, NaOH Br₂ 1 eq 120 °C 1) NaH 2) EtI 3) Poison Catalyst /H₂ 4) 03, -78°C; Zn H HO OH
- O E. .1. Which of the following statements about ethylene (CH2-CH2) molecule is/are false? Both carbons are sp² hybridized. The C=C bond length is shorter than the C-C length in ethane. It has a total of two pi bonds. The entire molecule has a planar geometry. а. b. с. d. 2. Which of the following statements regarding the El mechanism is/are false? Reactions by the El mechanism are unimolecular in the rate-determining step. b. а. Reactions by the El mechanism are generally first order. Reactions by the El mechanism usually occur in one step. Reactions by the El mechanism are multi-step reactions. с. d.Determine the major organic products for the reactions in addition to whether they are racemic or not?
- Fill in the missing information for the reaction shown: NO3 + H2 --> NO2° + H2O deltaGo' = kJ Under standard physiological conditions, this reaction is gonic2. Fill the missing reagents or products for the incomplete reaction schemes shown below (only Reagent A or Reagent B will react in significant quantities). F (1 mmol) Reagent A (1 mmol) Reagent B (1 mmol) Major Product from Reagent A Major Product from Reagent B Explain the selectivity observed in this reaction using words and drawings. Br NaNH2 Br NH3, -35 °C Вrz, FeBr3 Draw the mechanism for the transformation shown above. Be sure to draw the important resonance structures that account for the regioselectivity observed in this reaction.7. Reaction Scheme. NH₂ NH2 or two differnet methods (no same steps/reagents) C5H12N2 1. xs Mel, xs K2CO3 2. Ag2O, H₂O 3. heat Br2, xs NaOH, xs H₂O OHC 1.03 2. DMS CHO
