Consider a hypothetical chemical reaction:A+B C+D→>>(In this equation A, B, C and D stand for some unknown chemical formulas.)Here is an energy diagram for the reaction:energy(kJ/mol)400300-A + BC + D200.1000reaction coordinateUse the energy diagram to answer these questions.What is the heat of reaction?Is the reaction exothermic or endothermic?Can you determine the activation energy?☐ kJ/molExothermicEndothermicNeitherYes, it's ☐ kJ/molNo.Can you determine the activation energy of the reverse reaction?Yes,it's ☐ kJ/molNo.C+DA+BХ

Potential energy diagram: Reactants: The initial molecules in the left side of the reaction are…

Answered: Consider a hypothetical chemical…

General, Organic, and Biological Chemistry

7th Edition

ISBN:9781285853918

Author:H. Stephen Stoker

Publisher:H. Stephen Stoker

Chapter9: Chemical Reactions

Section: Chapter Questions

Problem 9.43EP

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Enthalpy a A 100.-g sample of water is placed in an insulated container and allowed to come to room temperature at 21C. To heat the water sample to 41C, how much heat must you add to it? b Consider the hypothetical reaction,2X(aq)+Y(l)X2Y(aq)being run in an insulated container that contains 100. g of solution. If the temperature of the solution changes from 21C to 31C, how much heat does the chemical reaction produce? How does this answer compare with that in part a? (You can assume that this solution is so dilute that it has the same heat capacity as pure water.) c If you wanted the temperature of 100. g of this solution to increase from 21C to 51C, how much heat would you have to add to it? (Try to answer this question without using a formula.) d If you had added 0.02 mol of X and 0.01 mol of Y to form the solution in part b, how many moles of X and Y would you need to bring about the temperature change described in part c. e Judging on the basis of your answers so far, what is the enthalpy of the reaction 2X(aq) + Y(l) X2Y(aq)?
How much heat is released when a mixture containing 10.0 g NH3 and 20.0 g O2 reacts by the following equation? 4NH3(g)+5O2(g)4NO(g)+6H2O(g);H=906kJ
The equation for the fermentation of glucose to alcohol and carbon dioxide is: C6H12O6(aq) 2C2H5OH(aq) + 2CO2(g) The enthalpy change for the reaction is 67 kJ. Is this reaction exothermic or endothermic? Is energy, in the form of heat, absorbed or evolved as the reaction occurs?
Graphite is burned in oxygen to give carbon monoxide and carbon dioxide. If the product mixture is 33% CO and 67% CO2 by mass, what is the heat from the combustion of 1.00 g of graphite?
Define each of the following terms: a. heat b. energy c. work d. system e. surroundings f. exothermic reaction g. endothermic reaction h. enthalpy of reaction i. kinetic energy j. potential energy
Hypothetical elements A2 and B2 react according to the following equation, forming the compound AB. A2(aq)+B2(aq)2AB(aq);H=+271kJ/mol If solutions A2(aq) and B2(aq), starting at the same temperature, are mixed in a coffee-cup calorimeter, the reaction that occurs is a exothermic, and the temperature of the resulting solution rises. b endothermic, and the temperature of the resulting solution rises. c endothermic, and the temperature of the resulting solution falls. d exothermic, and the temperature of the resulting solution falls. e exothermic or endothermic, depending on the original and final temperatures.
A rebreathing gas mask contains potassium superoxide, KO2, which reacts with moisture in the breath to give oxygen. 4KO2(s)+2H2O(l)4KOH(s)+3O2(g) Estimate the grams of potassium superoxide required to supply a persons oxygen needs for one hour. Assume a person requires 1.00 102 kcal of energy for this time period. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 1.00 102 kcal of heat, calculate the amount of oxygen consumed and hence the amount of KO2 required. The ff0 for glucose(s) is 1273 kJ/mol.
How much heat is required to raise the temperature of 100. grams of water from 25C near room temperature to 100.C its boiling point? The specific heat of water is approximately 4.2Jperg-K. a.3.2104J b.32J c.4.2104J d.76J
The equation for the combustion of 2 mol of butane can be written 2C4H10(g)+O2(g)8CO2(g)+10H2O(g);HO Which of the following produces the least heat? a Burning 1 mol of butane. b Reacting 1 mol of oxygen with excess butane. c Burning enough butane to produce 1 mol of carbon dioxide. d Burning enough butane to produce 1 mol of water. e All of the above reactions (a, b, c, and d) produce the same amount of heat.
How much heat, in kilojoules, must be removed to decrease the temperature of a 20.0-g bar of aluminum from 34.2 C to 22.5 C? (See Table 5.1 for the specific heat of aluminum.) TABLE 5.1 Specific Heats of Some Common Substances
9.58 For the reaction C2H2(g)+2H2(g)C2H6,H=136 kJ. What are the ratios that can be defined between moles of substances and energy?
9.89 A sample of gas is 80.0% CH4 and 20.0% C2H6 by mass. What is the heat from the combustion of 1.00 g of this mixture? Assume the products are CO2 (g) and H2O (l).

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