O11 CH,COOH /E 0.2 0.8 0.4 XW 0.6 XE 0.6 0.4 P a, a 0.8 0.2 1ZW 0.2 a H,0 ;O CHCI, 0.4 0.6 0.8 1 Figure 5E.4 The phase diagram, at fixed temperature and pressure, of the three-component system ethanoic acid (E), trichloromethane (T), and water (W). Only some of the tie lines have been drawn in the two-phase region. All points along the line a correspond to trichloromethane and water present in the same ratio.
O11 CH,COOH /E 0.2 0.8 0.4 XW 0.6 XE 0.6 0.4 P a, a 0.8 0.2 1ZW 0.2 a H,0 ;O CHCI, 0.4 0.6 0.8 1 Figure 5E.4 The phase diagram, at fixed temperature and pressure, of the three-component system ethanoic acid (E), trichloromethane (T), and water (W). Only some of the tie lines have been drawn in the two-phase region. All points along the line a correspond to trichloromethane and water present in the same ratio.
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
Related questions
Question
Refer to the ternary phase diagram in Fig. 5E.4.
a.) How many phases does a mixture of these liquids have?
Liquid | Amount (mol) | XT | XW | XE |
A | 15 | 0.5 | 0.25 | 0.25 |
B | 20 | 0.33 | 0.33 | 0.33 |
C | 7.5 | 0.1 | 0.8 | 0.1 |
b.) For the mixtures in letter a, What are the composition of the phases? If there are two phases, what are the compositions of the trichloromethane-rich and water-rich phases?
Expert Solution
Step 1
Single-phase and two phases exist in three components mixture. The equilibrium of these three components in the mixture is represented by the phase diagram .The phase diagram is called as ternary phase diagram or triangular diagram. The curve in the diagram separates the number of phases.
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