You are going to prepare a silicone polymer, and one of the starting materials is dichlorodimethylsilane, SiCl2(CH3)2. You need its normal boiling point and to measure equilibrium vapor pressures at various temperatures.What is the normal boiling point of dichlorodimethylsilane?Plot these data as ln P versus 1/TAt what temperature does the liquid have an equilibrium vapor pressure of 250 mm Hg? At what temperature is it 650 mm Hg?Calculate the molar enthalpy of vaporization for dichlorodimethylsilane using the Clausius–Clapeyron equation. Temperature (°C)Vapor Pressure (atm)-68.40.132-45.40.526- 33.61.000- 18.72.004.75.0025.710.0050.120.00

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Introduction to Chemical Engineering Thermodynamics

8th Edition

ISBN:9781259696527

Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Chapter1: Introduction

Section: Chapter Questions

Problem 1.1P

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You are going to prepare a silicone polymer, and one of the starting materials is dichlorodimethylsilane, SiCl₂(CH₃)₂. You need its normal boiling point and to measure equilibrium vapor pressures at various temperatures.

What is the normal boiling point of dichlorodimethylsilane?
Plot these data as ln P versus 1/T
At what temperature does the liquid have an equilibrium vapor pressure of 250 mm Hg? At what temperature is it 650 mm Hg?
Calculate the molar enthalpy of vaporization for dichlorodimethylsilane using the Clausius–Clapeyron equation.

Temperature (°C)
Vapor Pressure (atm)
-68.4
0.132
-45.4
0.526
- 33.6
1.000
- 18.7
2.00
4.7
5.00
25.7
10.00
50.1
20.00

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