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4. Find the fugacity (Pa) of ice (p = 0.915 g/cm³) at -10 °C and: ) P= Pat (i.e., at the sublimation pressure) - P=100 MPa (b) (

4. Find the fugacity (Pa) of ice (p = 0.915 g/cm³) at -10 °C and: ) P= Pat (i.e., at the sublimation pressure) - P=100 MPa (b) (

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Table 6 has been attached 

17 Deg C 0.0 Pa -0 611.153 -1 562.675 -2 517.724 -3 476.068 -4 437.488 -5 401.779 -6 368.748 -7 338.212 -8 310.001 -9 283.955 -10 259.922 - 11 237.762 -12 217.342 - 13 198.538 -14 181.233 -15 165.319 210 - 16 150.694 -17 137.263 - 18 124.938 -19 113.634 - 20 103.276 -21 93.7904 -22 -23 85.1104 77.1735 69.9217 -24 -25 - 26 63.3008 57.2607 51.7546 -27 -28 46.7393 - 29 42.1748 -30 38.0238 34.2521 30.8277 -31 -32 -33 -34 -35 27.7214 24.9059 22.3563 20.0494 17.9640 16.0805 -36 -37 -38 -39 -40 41 14.3809 12.8486 11.4685 0.1 Pa 606.140 558.025 513.414 472.075 433.791 398.358 365.585 335.289 307.302 281.464 257.624 235.644 215.391 196.742 179.581 900 163.800 149.299 135.982 123.763 112.557 102.289 92.8872 84.2842 76.4184 69.2321 62.6715 56.6868 51.2317 46.2632 41.7417 37.6301 33.8945 30.5032 27.4272 24.6394 22.1150 19.8312 17.7669 15.9025 14.2204 12.7040 11.3383 0.2 Pa 601.164 553.411 509.136 468.112 430.123 394.964 362.446 332.389 304.624 278.992 255.345 233.543 1061 213.456 194.961 177.942 162.294 147.915 134.713 122.598 111.489 101.311 91.9920 83.4655 75.6701 68.5487 62.0479 56.1182 50.7136 45.7916 41.3126 37.2402 33.5404 30.1819 27.1358 24.3755 21.8762 19.6152 17.5717 15.7264 14.0615 12.5609 11.2095 0.3 Pa 596.225 548.830 504.891 464.180 426.483 391.597 359.333 329.512 301.967 276.540 253,084 231.459 211.537 193, 194 210 176.318 160.801 146,544 133.453 121.443 110.431 100.341 91.1047 82.6540 74.9286 67.8716 61.4300 55.5548 50.2003 45.3244 40.8877 36.8540 33.1897 29.8637 26.8474 24.1142 21.6397 19.4014 17.3786 15.5521 13.9043 12.4 11.0820 TABLE 6. Saturation vapor pressure over ice 0.6 Pa 581.630 535.297 492.349 452.564 415.731 381.651 350.138 321.017 294.124 0.4 Pa 591.323 544.285 500.679 460.278 422.871 388.256 356.244 326.658 299.332 274.108 250.841 229.393 209.633 191.442 174.706 159.320 145.184 132.205 120.298 109.381 99.3809 90.2253 81.8498 74.1937 67.2005 60.8178 54.9966 49.6919 44.8616 40.4667 36.4714 32.8423 29.5486 26.5617 23.8555 21.4056 19.1898 17.1874 15.3795 13.7488 10.9559 0.5 Pa 586.458 539.774 496.498 456.406 419.287 384.940 353.179 323.826 296.717 271.696 248.617 227.343 207.745 189.705 173.109 157.852 143.835 130.968 119.163 108.341 98.4284 89.3537 81.0528 73.4655 66.5356 60.2112 54.4436 49.1882 44.4031 40.0498 36.0926 32.4983 29.2365 26.2789 23.5993 21.1739 18.9803 16.9982 15.2088 13.5948 10.8311 269.303 246.410 225.310 205.873 187.982 171.524 156.396 142.498 129.741 118.038 107.310 97.4843 88.4898 80.2629 72.7438 65.8768 59.6101 53.8958 48.6892 43.9489 39.6368 35.7173 32.1577 RESP 28.9275 25.9988 23.3457 20.9444 18.7729 16.8108 15.0397 13.4424 10.7076 0.7 Pa 576.837 530.853 488.232 448.751 412.202 378.387 347.121 318.230 291.551 266.929 244.222 223.293 204.017 186.274 169.953 154.952 141.173 128.524 116.923 106.288 96.5485 87.6336 79.4801 72.0286 65.2239 59.0146 53.3530 48.1948 43.4991 39.2278 35.3457 31.8203 28.6215 25.7215 23.0947 20.7173 18.5675 16.6254 14.8725 13.2916 674 10.5854 0.8 Pa 572.081 526.444 484.146 444.968 408.700 375.149 344,128 315.465 288.998 264.575 242.051 221.293 202.175 184.579 168.396 153.521 139.858 127.318 115.817 105.275 95.6210 86.7850 78.7043 71.3199 64.5770 58.4245 52.8152 47.7051 43.0534 38.8226 34.9776 31.4862 28.3185 25.4469 22.8461 20.4924 18.3643 16.4419 14.7069 13.1424 11.7330 10.4645 0.9 Pa 567.360 522.067 480.091 441.213 405.226 371.936 341.158 312.722 286.467 262.239 239.898 219.309 200.349 182.899 166.851 152.101 138.555 126.123 114.721 104.271 94.7016 85.9439 77.9355 70.6176 63.9360 57.8399 52.2824 47.2199 42.6120 38.4213 34.6131 31.1554 28.0185 25.1751 22.5999 20.2698 18.1631 16.2603 14.5430 12.9947 11.6000 10.3449 Derivative Pa/K 48.7738 45.2441 41.9451 38.8634 35.9864 33.3021 30.7990 28.4662 26.2936 24.2713 22.3900 20.6412 19.0163 17.5077 16.1079 14.8099 13.6070 12.4932 11.4624 10.5091 9.62823 8.81467 8.06388 7.37151 6.73347 6.14595 5.60533 5.10825 4.65155 4.23227 3.84764 3.49509 3.17218 2.87668 2.60647 2.35960 2.13424 1.92868 1.74136 1.57080 1.41564 1.27461
Transcribed Image Text:17 Deg C 0.0 Pa -0 611.153 -1 562.675 -2 517.724 -3 476.068 -4 437.488 -5 401.779 -6 368.748 -7 338.212 -8 310.001 -9 283.955 -10 259.922 - 11 237.762 -12 217.342 - 13 198.538 -14 181.233 -15 165.319 210 - 16 150.694 -17 137.263 - 18 124.938 -19 113.634 - 20 103.276 -21 93.7904 -22 -23 85.1104 77.1735 69.9217 -24 -25 - 26 63.3008 57.2607 51.7546 -27 -28 46.7393 - 29 42.1748 -30 38.0238 34.2521 30.8277 -31 -32 -33 -34 -35 27.7214 24.9059 22.3563 20.0494 17.9640 16.0805 -36 -37 -38 -39 -40 41 14.3809 12.8486 11.4685 0.1 Pa 606.140 558.025 513.414 472.075 433.791 398.358 365.585 335.289 307.302 281.464 257.624 235.644 215.391 196.742 179.581 900 163.800 149.299 135.982 123.763 112.557 102.289 92.8872 84.2842 76.4184 69.2321 62.6715 56.6868 51.2317 46.2632 41.7417 37.6301 33.8945 30.5032 27.4272 24.6394 22.1150 19.8312 17.7669 15.9025 14.2204 12.7040 11.3383 0.2 Pa 601.164 553.411 509.136 468.112 430.123 394.964 362.446 332.389 304.624 278.992 255.345 233.543 1061 213.456 194.961 177.942 162.294 147.915 134.713 122.598 111.489 101.311 91.9920 83.4655 75.6701 68.5487 62.0479 56.1182 50.7136 45.7916 41.3126 37.2402 33.5404 30.1819 27.1358 24.3755 21.8762 19.6152 17.5717 15.7264 14.0615 12.5609 11.2095 0.3 Pa 596.225 548.830 504.891 464.180 426.483 391.597 359.333 329.512 301.967 276.540 253,084 231.459 211.537 193, 194 210 176.318 160.801 146,544 133.453 121.443 110.431 100.341 91.1047 82.6540 74.9286 67.8716 61.4300 55.5548 50.2003 45.3244 40.8877 36.8540 33.1897 29.8637 26.8474 24.1142 21.6397 19.4014 17.3786 15.5521 13.9043 12.4 11.0820 TABLE 6. Saturation vapor pressure over ice 0.6 Pa 581.630 535.297 492.349 452.564 415.731 381.651 350.138 321.017 294.124 0.4 Pa 591.323 544.285 500.679 460.278 422.871 388.256 356.244 326.658 299.332 274.108 250.841 229.393 209.633 191.442 174.706 159.320 145.184 132.205 120.298 109.381 99.3809 90.2253 81.8498 74.1937 67.2005 60.8178 54.9966 49.6919 44.8616 40.4667 36.4714 32.8423 29.5486 26.5617 23.8555 21.4056 19.1898 17.1874 15.3795 13.7488 10.9559 0.5 Pa 586.458 539.774 496.498 456.406 419.287 384.940 353.179 323.826 296.717 271.696 248.617 227.343 207.745 189.705 173.109 157.852 143.835 130.968 119.163 108.341 98.4284 89.3537 81.0528 73.4655 66.5356 60.2112 54.4436 49.1882 44.4031 40.0498 36.0926 32.4983 29.2365 26.2789 23.5993 21.1739 18.9803 16.9982 15.2088 13.5948 10.8311 269.303 246.410 225.310 205.873 187.982 171.524 156.396 142.498 129.741 118.038 107.310 97.4843 88.4898 80.2629 72.7438 65.8768 59.6101 53.8958 48.6892 43.9489 39.6368 35.7173 32.1577 RESP 28.9275 25.9988 23.3457 20.9444 18.7729 16.8108 15.0397 13.4424 10.7076 0.7 Pa 576.837 530.853 488.232 448.751 412.202 378.387 347.121 318.230 291.551 266.929 244.222 223.293 204.017 186.274 169.953 154.952 141.173 128.524 116.923 106.288 96.5485 87.6336 79.4801 72.0286 65.2239 59.0146 53.3530 48.1948 43.4991 39.2278 35.3457 31.8203 28.6215 25.7215 23.0947 20.7173 18.5675 16.6254 14.8725 13.2916 674 10.5854 0.8 Pa 572.081 526.444 484.146 444.968 408.700 375.149 344,128 315.465 288.998 264.575 242.051 221.293 202.175 184.579 168.396 153.521 139.858 127.318 115.817 105.275 95.6210 86.7850 78.7043 71.3199 64.5770 58.4245 52.8152 47.7051 43.0534 38.8226 34.9776 31.4862 28.3185 25.4469 22.8461 20.4924 18.3643 16.4419 14.7069 13.1424 11.7330 10.4645 0.9 Pa 567.360 522.067 480.091 441.213 405.226 371.936 341.158 312.722 286.467 262.239 239.898 219.309 200.349 182.899 166.851 152.101 138.555 126.123 114.721 104.271 94.7016 85.9439 77.9355 70.6176 63.9360 57.8399 52.2824 47.2199 42.6120 38.4213 34.6131 31.1554 28.0185 25.1751 22.5999 20.2698 18.1631 16.2603 14.5430 12.9947 11.6000 10.3449 Derivative Pa/K 48.7738 45.2441 41.9451 38.8634 35.9864 33.3021 30.7990 28.4662 26.2936 24.2713 22.3900 20.6412 19.0163 17.5077 16.1079 14.8099 13.6070 12.4932 11.4624 10.5091 9.62823 8.81467 8.06388 7.37151 6.73347 6.14595 5.60533 5.10825 4.65155 4.23227 3.84764 3.49509 3.17218 2.87668 2.60647 2.35960 2.13424 1.92868 1.74136 1.57080 1.41564 1.27461
4. Find the fugacity (Pa) of ice (p = 0.915 g/cm³) at -10 °C and: ) P= Psat (i.e., at the sublimation pressure) --) P = 100 MPa (b) ( Data on vapor pressure of ice can be found in Table 6 of: Wexler, A. (1977). Vapor pressure formulation for ice. Journal of Research of the National Bureau of Standards. Section A, Physics and Chemistry, 81(1), 5. Included in
Transcribed Image Text:4. Find the fugacity (Pa) of ice (p = 0.915 g/cm³) at -10 °C and: ) P= Psat (i.e., at the sublimation pressure) --) P = 100 MPa (b) ( Data on vapor pressure of ice can be found in Table 6 of: Wexler, A. (1977). Vapor pressure formulation for ice. Journal of Research of the National Bureau of Standards. Section A, Physics and Chemistry, 81(1), 5. Included in
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