Acetone is added to n-propylamine that also contains HOAC/OAC¯ at pH 4.8. Which of the following best describes the sequence of mechanistic steps for this reaction? Please note the following abbreviations: p.t. = proton transfer; Nu attack = nucleophilic attack; loss of LG = loss of leaving group; SN2 = a concerted nucleophilic attack and loss of a leaving group; E2 = a concerted bimolecular elimination reaction; (Nu attack, p.t.) = a concerted nucleophilic attack and proton transfer; (p.t., Loss of LG) = a concerted proton transfer and loss of a leaving group; and N.R. = no reaction. SN2 Nu attack; p.t. p.t., Nu attack, p.t., p.t., loss of LG, Nu attack, p.t. Loss of LG, p.t., Nu attack, p.t., loss of LG, p.t. Nu attack, p.t., loss of LG, p.t., p.t., Nu attack, loss of LG E2 O N.R. O (Nu attack, p.t.), p.t., p.t., loss of LG, p.t. p.t., Nu attack, p.t., p.t., loss of LG, p.t. O p.t., Nu attack, p.t., p.t., (p.t., loss of LG)
Acetone is added to n-propylamine that also contains HOAC/OAC¯ at pH 4.8. Which of the following best describes the sequence of mechanistic steps for this reaction? Please note the following abbreviations: p.t. = proton transfer; Nu attack = nucleophilic attack; loss of LG = loss of leaving group; SN2 = a concerted nucleophilic attack and loss of a leaving group; E2 = a concerted bimolecular elimination reaction; (Nu attack, p.t.) = a concerted nucleophilic attack and proton transfer; (p.t., Loss of LG) = a concerted proton transfer and loss of a leaving group; and N.R. = no reaction. SN2 Nu attack; p.t. p.t., Nu attack, p.t., p.t., loss of LG, Nu attack, p.t. Loss of LG, p.t., Nu attack, p.t., loss of LG, p.t. Nu attack, p.t., loss of LG, p.t., p.t., Nu attack, loss of LG E2 O N.R. O (Nu attack, p.t.), p.t., p.t., loss of LG, p.t. p.t., Nu attack, p.t., p.t., loss of LG, p.t. O p.t., Nu attack, p.t., p.t., (p.t., loss of LG)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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