Chapter7: Statistical Data Treatment And Evaluation
Section: Chapter Questions
Problem 7.10QAP
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In this reaction, why doesn't the NH2 group trigger an elimination instead of the substitution reaction seen in the picture?
Why can't the -NH2 remove a proton, causing the C-H bond to collapse and form a triple bond (benzyne), and the Cl is removed as a leaving group?
![KNH2
+ KCI
NH3
-30 °C
NH2
traditional SAr
reactions require
chloro is only
moderately
electron-withdrawing
heat !](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F1e3757b9-2c73-44b9-b0b4-3a3249d79666%2Feb882325-8ccb-4faf-846b-f9f1140cc9c2%2F4pcneie_processed.png&w=3840&q=75)
Transcribed Image Text:KNH2
+ KCI
NH3
-30 °C
NH2
traditional SAr
reactions require
chloro is only
moderately
electron-withdrawing
heat !
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