4) Vocabulary: words are given circle the correct one. a. A Robinson Annulation can occur with acetoacetate / malonic ester / both / neither Fill in the blanks with the appropriate vocabulary word. If two as the nucleophile, and with conjugated ester / conjugated ketone / epoxide / all/ none as the electrophile. The Robinson Annulation is a reaction followved by a reaction and always / sometimes / never gives a 6-member ring. b. It is always / sometimes / never possible to use base to form an acyl anion directly from an aldehyde. c. True / False Aliphatic heterocycles typically react like linear versions of the functional group. d. Claisen condensations require catalytic / 1 equivalent / large excess base, at least alpha hydrogens on the nucleophile, always /sometimes / never use an ester as an electrophile, and always / sometimes /never use an ester as a nucleophile. e. Reaction of a beta-ketoester with water, acid, and heat gives first a reaction, then will not work on a beta-diester and will /will not work on a 1,4-ketoester. and lastly This reaction will/

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Chapter1: Chemical Foundations
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4) Vocabulary:
words are given circle the correct one.
a. A Robinson Annulation can occur with acetoacetate / malonic ester / both / neither
Fill in the blanks with the appropriate vocabulary word. If two
as the nucleophile, and with conjugated ester / conjugated ketone / epoxide / all/
none as the electrophile. The Robinson Annulation is a
reaction followed by a
reaction and always / sometimes /
never gives a 6-member ring.
b. It is always / sometimes / never possible to use base to form an acyl anion directly
from an aldehyde.
c. True / False.Aliphatic heterocycles typically react like linear versions of the
functional group.
d. Claisen condensations require catalytic / 1 equivalent / large excess base, at least
2 alpha hydrogens on the nucleophile, always / sometimes / never use an
ester as an electrophile, and always / sometimes / never use an ester as a nucleophile.
e. Reaction of a beta-ketoester with water, acid, and heat gives first a
reaction, then
and lastly
This reaction will/
will not work on a beta-diester and will / will not work on a 1,4-ketoester.
Transcribed Image Text:4) Vocabulary: words are given circle the correct one. a. A Robinson Annulation can occur with acetoacetate / malonic ester / both / neither Fill in the blanks with the appropriate vocabulary word. If two as the nucleophile, and with conjugated ester / conjugated ketone / epoxide / all/ none as the electrophile. The Robinson Annulation is a reaction followed by a reaction and always / sometimes / never gives a 6-member ring. b. It is always / sometimes / never possible to use base to form an acyl anion directly from an aldehyde. c. True / False.Aliphatic heterocycles typically react like linear versions of the functional group. d. Claisen condensations require catalytic / 1 equivalent / large excess base, at least 2 alpha hydrogens on the nucleophile, always / sometimes / never use an ester as an electrophile, and always / sometimes / never use an ester as a nucleophile. e. Reaction of a beta-ketoester with water, acid, and heat gives first a reaction, then and lastly This reaction will/ will not work on a beta-diester and will / will not work on a 1,4-ketoester.
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