1. Which of these will undergo a rearrangement during the reaction 2. For reaction D - is HBr the nucleophile or electrophile? 3. For each of the reactions - a. Complete the reaction, showing the mechanism by using b. Draw the intermediate – showing the carbocation and an C. Draw and write the name of the final product.
1. Which of these will undergo a rearrangement during the reaction 2. For reaction D - is HBr the nucleophile or electrophile? 3. For each of the reactions - a. Complete the reaction, showing the mechanism by using b. Draw the intermediate – showing the carbocation and an C. Draw and write the name of the final product.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:## Problem Set
1. **Which of these will undergo a rearrangement during the reaction?**
2. **For reaction D – is HBr the nucleophile or electrophile?**
3. **For each of the reactions:**
- a. Complete the reaction, showing the mechanism by using arrows.
- b. Draw the intermediate, showing the carbocation and any rearrangements.
- c. Draw and write the name of the final product.
### Naming Compounds with Halides
To name a compound with a halide attached, treat the halide as a substituent, indicating its position.
For example:
- Bromine = bromo
- Chlorine = chloro
### Reaction Diagrams
#### Diagram (b)
- **Reactants:** A branched alkene is reacted with HCl, indicated by an arrow pointing to the right.
- **Mechanism:** The reaction likely involves the formation of a carbocation intermediate, followed by the attack of the Cl⁻ ion.
#### Diagram (d)
- **Reactants:** A linear alkene structure is reacted with HBr, indicated by an arrow pointing to the right.
- **Mechanism:** The reaction involves protonation to form a carbocation intermediate, followed by nucleophilic attack by the Br⁻ ion.
Students are encouraged to complete the reaction mechanisms by illustrating arrow-pushing, drawing intermediates, and naming the final products based on IUPAC nomenclature.
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