4 pts total)re is Aromatic (A),(circle one)A AANion with Cl₂/FeCls. (6 pts)acids shown to right) (6 pts)al31. Consider the Friedel-Crafts (FC) alkylation of N-phenylacetamide (shown below) in which reaction with1-chloropropane and AlCl3 produces two isomers of isopropyl N-phenylacetamide. (20 pts)1. Draw the complete reaction mechanism for the formation of the ortho product (para is also formed) (10 pts)2. Is this reaction faster or slower than the similar FC reaction starting with benzene (C6H6)? Explain why. (4 pts)3. Explain why this reaction produces the ortho and para products (but not meta). (6 pts)Use your mechanism to help explain parts #2 and #3. Use additional drawings and words as needed.toAICIN-phenylacetamide455staAHO O00 10HСОИН08HНИMOHO HOHO10

Answered: Image /qna-images/answer/f78ffb1c-aa29-4c8c-8474-6d1c82e7f0c1.jpg

Answered: 4 pts total) re is Aromatic (A),…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Propose a curved arrow mechanism to account for the formation of compound C.
2. For the following amines A and B, show all of the Hoffman elimination products. If one product is favored, please indicate it as the major product. 8. IZ: A.
3.11: The enzyme catalyzing the reaction below, thought to participate in the fermentation of lysine in bacteria, was recently identified and characterized (J. Biol. Chem. 2011, 286, 27399). Propose a likely chanism. Hint: the mechanism involves two separate carbon-carbon bond forming and bond breaking steps. C of acetyl CoAis identified with a red dot to help you trace it through to the product. NH3 0 NH3 0 co H3C .CO2 SCOA SCOA
A problem in dyeing fabrics is the degree of fastness of the dye to the fabric. Many of the early dyes were surface dyes; that is, they did not bond to the fabric, with the result that they tended to wash off after repeated laundering. Indigo, for example, which gives the blue color to blue jeans, is a surface dye. Color fastness can be obtained by bonding a dye to the fabric. The first such dyes were the so-called reactive dyes, developed in the 1930s for covalently bonding dyes containing-NH, groups to cotton, wool, and silk fabrics. In the first stage of the first-developed method for reactive dyeing, the dye is treated with cyanuric chloride, which links to the fabric through the amino group of the dye. The remaining chlorines are then displaced by the-OH groups of cotton (cellulose) or the-NH, groups of wool or silk (both proteins). CI -Cotton Dye-NH, Но-Сotton N' CI CI Dye-NH CI Dye-NH 'N. 0-Cotton Cyanuric chloride A reactive dye Dye covalently bonded to cotton Propose a…
2. In Experiment 4B, it was shown from the NMR spectrum that the meta-di-substituted Nitration product had been recorded as a major product: COOME COOME HNO3 H,SO, NO2 Major product However, there were two other possible but less favorable routes, i.e. ortho- or para- positions for the nitronium to attack the aromatic ring with. Draw the H-NMR spectrum for Methyl p-Nitrobenzoate in case the substitution takes place at the para-position. Pay attention to the chemical shift, the splitting pattern, and approximate the integration in your spectra. Methyl p-Nitrobenzoate 3.0 2.5 2.0 1.5 - 1.0- 0.5 4 3. 2 1. 10 6. 8.
3,) you have now eliminated one substitution site and should have two possible sites remaining. Provide a mechanism for the formation of each of the two remaining products. You should include all possible. Resident structures for the cat on intermediates. There should be four resident structures in each mechanism. You do not need to show the mechanism for the formation of the electrify you may assume that only a single iodine will add to the ring. a. b. GOLDEST GAD SE 1029 OH H OH 02AB o 1o1 meiasdoorn woms bevis song of olds pel I+ noboibong tombong 10 to asiqisminoviowTill bris H₂O, EtOH naut nobibba as gada tasest 30 no odt to toubong Input sdr lo notaxillaryn I+ bouborg on to ving di salmsibb or O etshqoqs edt onimaob or atob MM O bax H seu zie.baz anoitecu dale19 H₂O, EtOH lliw gan snated a no quorg lanoituut invellib.noimadue shamore siliqotools al Hoib blaos tad aquosy Insoitonut oor za milline V.mobest ad not sila noistade sitt lenoiraut dues bleno) nobedog ad to goitool…

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