Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:2. In Experiment 4B, it was shown from the NMR spectrum that the meta-di-substituted Nitration product had
been recorded as a major product:
COOME
COOME
HNO3
H,SO,
NO2
Major product
However, there were two other possible but less favorable routes, i.e. ortho- or para- positions for the nitronium
to attack the aromatic ring with. Draw the H-NMR spectrum for Methyl p-Nitrobenzoate in case the
substitution takes place at the para-position. Pay attention to the chemical shift, the splitting pattern, and
approximate the integration in your spectra.
Methyl p-Nitrobenzoate
3.0
2.5
2.0
1.5 -
1.0-
0.5
4
3.
2
1.
10
6.
8.
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