3Energy (EU) Set A Set B Set C2124418113293290161416a) Demonstrate that the sets have the same energy.b) Determine which of the sets is the most probable.c) For the most probable set, is the energy distribution consistent with a Boltzmann distribution?Explain your answer.

Answer:(a) All units have the same strength: (22 , textual cοntent{eu}).(b) The mοst pοssibly set…

Answered: 3 Energy (EU) Set A Set B Set C 2 1 2 4…

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter17: Statistical Thermodynamics: Introduction

Section: Chapter Questions

Problem 17.17E

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Consider the molecules: CH2=CH-CH=CH-CH=CH-CH=CH-CH=CH2. Let’s assume that the 10 electrons that make up the double bonds can exist everywhere along the carbon chains. The electrons can then be considered as particles in a box; the ends of the molecule correspond to the boundaries of the box with a finite or zero potential energy inside. In this “molecular box”, 2 electrons can occupy an energy level. What are quantum states that the electrons from this molecule can occupy in the ground state? Note that the length of a C-C bond is about 1.54A and the length of a C=C bond is 1.34A to allow you to estimate the length of the “molecular box”
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3 Energy (EU) Set A Set B Set C 2 1 2 4 4 1 8 11 329 3 2 9 0 16 14 16 a) Demonstrate that the sets have the same energy. b) Determine which of the sets is the most probable. c) For the most probable set, is the energy distribution consistent with a Boltzmann distribution? Explain your answer.