b,c,e ex d.b.CH3OHCH3OHC.e.OHCH3OHCH3CISOCI₂OH Pyndine7Cl²Thyonyl ChlorideCI d. 2-propanolH₂ Soy at high heat then hyfor H₂SO4 againe. 2-bromopropaneHBr to convert to alkyl bif. propanoneLially to dryether, low to니7. Show how to convert the following compounds:CH3a.OHCH3CH3OHH₂SH₂O0CH3

Answered: Image /qna-images/answer/f8f9a409-9419-4451-9777-beb9f3fbb0a8.jpg

Answered: d. b. CH3 OH CH3 OH C. e. OH CH3 OH CH3…

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter17: Alcohols And Phenols

Section17.SE: Something Extra

Problem 67AP: Dehydration of trans-2-methylcyclopentanol with POCl3 in pyridine yields predominantly...

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Which is the major product of the following reaction ? CH,CH, H;C-c-CH,CH, CH,CH, H,C-CH-CH=CH2 1 CH;CH, H,C-CH-CH-CH, heat II CH,CH, H,C-c-CH-CH, CHCH; H,C-č-CH,CH, OH II IV a. I b. II C.I d. IV
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Give the major product(s) of the following reaction. I □ CH3OH □ CH3O™ H OH OH 1) DIBAL - H (-78°C) (1 mole) 2) H3O+ ? There is no reaction under these conditions or thecorrect product is not listed here.
6. The product(s) of the following reaction dd blow di CH2-CH2 excess HBr is/are: CH2 CH2 heat Od Al () (A od Ocf D (CHPPCOK (CHPCON G)D CH;CH2OCH,CH3 HO CH;CH,CH,CH,OH and CH;CH,CH2CH,Br II H t mol boumol toubong soinm od o CH2-CHBR HO CH2 CH2 BrCH-CH,CH-Cн,ОН and BrCH,CH,CH-CH,Br CityCHCH COM III IV A) I B) П O II D) IV E) None of these HO CH CH'OH
3. Show the mechanism for the acid catalyzed addition of H2O to the following ketone. OH H20 CH3 H* 4. The scheme below shows the reaction of a ketone, 2-propanone with methanol. OH :0 : || CH,-C-CH3 : ОН + H CH, c-CH3 CH;-C-CH3 N step 1 step 2 step 3 P CH,OH CH3 CH,OH step 4 + H OCH3 CH,-C-CH3 H - H,0 C-CH3 ÓCH, S CH; step 7 step 6 step 5 OCH3 i) Write the missing structures (N, O, Q and R) in the above reaction scheme. ii) Name the class of compounds P and S belong to? iii) This is an acid catalyzed reaction. What does this statement mean? iv) Draw the arrow diagram in step 6 to show how intermediate R is formed? Write the equation for this step ONLY. v) Steps 3 and 7 involve loss of a proton from the intermediate ions. Why is this step necessary?
What is the major product of the following reaction? CH3 CH2-C-CH3 + KOH Br CH3 CH-C-CH CH, CH2-C-CH IV. L. HO ОН Н CH3 CH-C-CH, CH CH=C-CH3 II V. CH3 CH2-CH-CH2OH II || O II IV
Which of the following is the final and major product of this reaction? C=CH I. II 00000 IV V + H₂O CCH3 C=CH₂ OH -CH₂CH H2SO4 HgSO4 IV. V. ? Ⓒ @ -CH=CH OH -CH-CH₂ OH OH
What is the best reagent used for the following reaction? H3C H3C ОН Н ? H- ? H3C H3C H. A O ВНз /Н202 .B Hg (OAC)2 / NABH4 .C O H30* /HgsO4 .D O Li /NH3
Oo.14. Subject:- Chemistry
Dehydration of trans-2-methylcyclopentanol with POCl3 in pyridine yields predominantly 3-methylcyclopentene. Is the stereochemistry of this dehydration syn or anti? Can you suggest a reason for formation of the observed product? (Make molecular models!)
Draw the structures of the organoboranes formed when borane reacts with each alkene below, including the regiochemistry and stereochemistry as appropriate. Propose a mechanism for each reaction.
As a rule, axial alcohols oxidize somewhat faster than equatorial alcohols. Which would you expect to oxidize faster, cis-4-tert-butylcyclo-hexanol or trans-4-tert-butylcyclohexanol? Draw the more stable chair conformation of each molecule.

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