4. Iodide ion is oxidized to hypoiodite ion, IO, by hypochlorite ion, CIO, in basic solution. The equation is OH- I (aq) + CIO (aq) →→ IO (aq) + Cl(aq) The following initial rate experiments were run and, for each, the initial rate of formation of IO was determined. (30 points) Experiment [I] (M) [CIO] (M) [OH-] (M) Initial Rate (*) Sec 1 0.010 0.020 0.010 12.2 x 10-2 2 0.020 0.010 0.010 12.2 x 10-2 3 0.010 0.010 0.010 6.1 x 10-2 4 0.010 0.010 0.030 3.0 x 10-2 a. What is the empirical rate law expression? b. Determine the values of x, y, and z from the empirical rate law expression?
4. Iodide ion is oxidized to hypoiodite ion, IO, by hypochlorite ion, CIO, in basic solution. The equation is OH- I (aq) + CIO (aq) →→ IO (aq) + Cl(aq) The following initial rate experiments were run and, for each, the initial rate of formation of IO was determined. (30 points) Experiment [I] (M) [CIO] (M) [OH-] (M) Initial Rate (*) Sec 1 0.010 0.020 0.010 12.2 x 10-2 2 0.020 0.010 0.010 12.2 x 10-2 3 0.010 0.010 0.010 6.1 x 10-2 4 0.010 0.010 0.030 3.0 x 10-2 a. What is the empirical rate law expression? b. Determine the values of x, y, and z from the empirical rate law expression?
Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.10PAE: For each of the following, suggest appropriate rate units Driving from one place to another Drying...
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If given the table below, what would the empirical rate law expression for the following equation:
I(aq) + ClO(aq) +OH^-1 reacts with IO(aq)+Cl(aq)
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