An acid-base indicator, HIn, dissociates according to the reaction shown in an aqueous solution. Ka, Hin HIn(aq) In (aq) + H+(aq) The protonated form of the indicator, HIn, has a molar absorptivity of 3199 M-1 cm-1 and the deprotonated form, In¯, has a molar absorptivity of 21910 M-1 cm at 440 nm. The pH of a solution containing a mixture of HIn and In is adjusted to 6.21. The total concentration of HIn and In is 0.000124 M. The absorbance of this solution was measured at 440 nm in a 1.00 cm cuvet and was determined to be 0.882. Calculate pK for HIn. pka, Hin
An acid-base indicator, HIn, dissociates according to the reaction shown in an aqueous solution. Ka, Hin HIn(aq) In (aq) + H+(aq) The protonated form of the indicator, HIn, has a molar absorptivity of 3199 M-1 cm-1 and the deprotonated form, In¯, has a molar absorptivity of 21910 M-1 cm at 440 nm. The pH of a solution containing a mixture of HIn and In is adjusted to 6.21. The total concentration of HIn and In is 0.000124 M. The absorbance of this solution was measured at 440 nm in a 1.00 cm cuvet and was determined to be 0.882. Calculate pK for HIn. pka, Hin
Chemistry by OpenStax (2015-05-04)
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ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
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Chapter15: Equilibria Of Other Reaction Classes
Section: Chapter Questions
Problem 82E: The simplest amino acid is glycine, H2NCH2CO2H. The common feature of amino acids is that they...
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Transcribed Image Text:An acid-base indicator, HIn, dissociates according to the reaction shown in an aqueous solution.
Ka, Hin
HIn(aq)
In (aq) + H+(aq)
The protonated form of the indicator, HIn, has a molar absorptivity of 3199 M-1 cm-1 and the deprotonated form, In¯, has a
molar absorptivity of 21910 M-1 cm at 440 nm. The pH of a solution containing a mixture of HIn and In is adjusted to 6.21.
The total concentration of HIn and In is 0.000124 M. The absorbance of this solution was measured at 440 nm in a 1.00 cm
cuvet and was determined to be 0.882. Calculate pK for HIn.
pka, Hin
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