Draw a Lewis structure for each, and state the type of octet - rule exception: (a) BH3; (b) AsF4; (c) SeC 14; (d) PF6; (e) CIO3 ;(f) H3PO3; (g) 03; (h) XeF2; (i) SbF4
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- Draw a Lewis structure for each species: (a) PF₅; (b) CCl₄;(c) H₃O⁺ ; (d) ICl₃; (e) BeH₂; (f) PH₂⁻; (g) GeBr₄; (h) CH₃;(i) BCl₃; (j) BrF₄⁺ ; (k) XeO₃; (l) TeF₄(c) PH3 (i) SF, Discussion: Which molecules are expected to violate the octet rule? Write the Lewis structures of the following molecules. (a) BeH2 (g) SeF4 (b) H2S (h) KrF;* (d) CF4 (i) PF 5 (e) IF3 (k) KrF2 (f) XEF4 (1) BCI3Write Lewis structures for the following molecules or ions, which have central atoms that do not obey the octet rule:
- (c) Write the Lewis structure for SC12, C13+, SOCI2, CIOCIO3(contains Cl-O-CI bond)1. Write Lewis symbols for the following atoms. (1pt each) (a) Kr (b) Ge (c) N (d) Ga (e) As (f) Rb 2. Write plausible Lewis structures for the following molecules that contain only single covalent bonds. (2 pts each) (а) FCI (b) I2 (c) SF2 (d) NF3 (е) Н-Те 3. By means of Lewis structures, represent bonding between the following pairs of elements (Your structures should show whether the bonding is essentially ionic or covalent): (2 pts each) (a) Cs and Br (b) H and Sb (c) B and Cl (d) Cs and Cl (e) Li and O (f) Cl and I 4. Assign formal charges to each of the atoms in the following structures. (3 pts each) (a) [H–C=C:]¯ (c) [CH3–CH-CH3]* (b) |2– :0: :0: 5. What is the formal charge of the indicated atom in each of the following structures? (2 pts each) (a) the central O atom in 03 (b) Al in AIH4- (c) Cl in Cl03 (d) Si in SiF62- (e) Cl in CIF3 6. Arrange the following elements in the order of decreasing electronegativity: fluorine, bromine, lithium, francium, silicon. (1 pt each per…Which of the following contains an ionic bond? (a) H2; (b) NaCl; (c) NaOH; (d) CH3ONa; (e) CH4; (f) HOCH2CH3;(g) LiNHCH3; (h) CH3CH2CO2K; (i) C6H5NH3Cl
- Write Lewis structures for the following: (a) H2CO (bothH atoms are bonded to C), (b) H2O2, (c) C2F6 (containsa C¬C bond), (d) AsO33 - , (e) H2SO3 (H is bonded to O),(f) NH2Cl2.Molecules containing only single covalent bonds are suitableWrite Lewis structures: (a) FCl; (b) I2; (c) SF2; (d) NF3; (e) H2Te4. Show the best Lewis structures, based on formal charge considerations (show these), for each of the following: (g) C20 (h) SCN cl04, (a) NF3 S20;2- (b) (с) NO2 SO3 (d) (e) N3 HỘI (i) G) NO2 (k) FOOF (1) ONCI (f)
- Draw all possible resonance structures for SO2, S0,, and SO. Use the resonance structures to solve the problems below. (a) Arrange these species in order of increasing S-O bond length (shortest bond first). O SO O SO O SO2 O SO2 O so;²- O SO O So3? O SO2 (b) Match each species with the number of covalent bonds predicted by Lewis structures to exist between an S atom and an O atom bonded to this S atom. (Hint: Average the number of bonds between S and an attached oxygen atom in a particular position using all of your resonance structures for the species that you are working on.) SO: -Select-v bonds between S and 0. -Select--- v bonds between S and O. SO2: Select-v bonds between S and O. (c) Match each species with the correct formal charge on the central S atom. SO: Select- charge on S. SO2: Select--v charge on S. SO32:-Select-vcharge on S. (d) Match each species with the average formal charge on an outside oxygen atom predicted by Lewis structures. so: -Select-vaverage charge on…Which of these atoms cannotserve as a central atom in a Lewis structure: (a) O; (b) He; (c) F; (d) H; (e) P? Explain.Write Lewis structures for the following:(a) SeF6(b) XeF4(c) SeCl3+(d) Cl2BBCl2 (contains a B–B bond)