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(c) Consider atomic oxygen gas at the temperature of 298.15 K. (i) Calculate its heat capacity at constant volume, assuming that the first two excited states have a non-negligible population. (ii) What would happen to the heat capacity at constant volume when the temperature increases to 1000 K? Discuss qualitatively. Data: The term symbols of the ground and first two excited states are (in increasing order): 3P2, 3P1 and 3Po; AV₁-2 = 158.5 cm; AV₁3 = 226.5 cm−¹

(c) Consider atomic oxygen gas at the temperature of 298.15 K. (i) Calculate its heat capacity at constant volume, assuming that the first two excited states have a non-negligible population. (ii) What would happen to the heat capacity at constant volume when the temperature increases to 1000 K? Discuss qualitatively. Data: The term symbols of the ground and first two excited states are (in increasing order): 3P2, 3P1 and 3Po; AV₁-2 = 158.5 cm; AV₁3 = 226.5 cm−¹

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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(c) Consider atomic oxygen gas at the temperature of 298.15 K. (i) Calculate its heat capacity at constant volume, assuming that the first two excited states have a non-negligible population. (ii) What would happen to the heat capacity at constant volume when the temperature increases to 1000 K? Discuss qualitatively. Data: The term symbols of the ground and first two excited states are (in increasing order): 3P2, 3P1 and 3Po; AV₁-2 = 158.5 cm; AV₁3 = 226.5 cm−¹
Transcribed Image Text:(c) Consider atomic oxygen gas at the temperature of 298.15 K. (i) Calculate its heat capacity at constant volume, assuming that the first two excited states have a non-negligible population. (ii) What would happen to the heat capacity at constant volume when the temperature increases to 1000 K? Discuss qualitatively. Data: The term symbols of the ground and first two excited states are (in increasing order): 3P2, 3P1 and 3Po; AV₁-2 = 158.5 cm; AV₁3 = 226.5 cm−¹
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