2. Chair Strain(a)Consider the following cyclohexane derivative. Circle the location (axial orfor each substituent in this molecule's most stable chair conformer.(b)(c) (FaxialequatorialBraxialequatorialBrCH3PhaxialequatorialPhCH3axialequatorialequatorial)Draw the chair conformer described in (a), adding only the substituents (not thehydrogen groups of those stereocenters) onto the template below.O Complete the table, indicating how many of each type of interaction is present in totalfor the chair conformer described in (a).gauche interactions between gauche interactionssubstituents and the ringbetween substituents1,3-diaxialinteractions betweensubstituents(d) (Draw the other conformer that results from a chair flip onto the template below. Mathe changes that happen in the chair flip, but don't make other changes. Only draw substituer

Answered: 2. Chair Strain (a) Consider the…

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter6: Alkanes & Alkenes

Section: Chapter Questions

Problem 10CTQ: Consider the Newman projection below. a. Draw a full Lewis structure of this molecule with...

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Consider the molecule 1-bromo-2-methylbutane. C3 and C4 should be drawn as Et as in theexample. This group is called an ethyl group and can be considered a sphere about twice the sizeof a methyl group. Draw the following Newman projections sighting down the C1C2 bond... a. The lowest potential energy conformation. b. The highest potential energy staggered conformation.
Consider the Newman projection below. a. Draw a full Lewis structure of this molecule with R1=Me,R2=Et , and R3=iPr . b. Given the sizes of these R groups (R3R2R1) , does the Newman projection above show thelowest potential energy conformation of this bond? If not, draw a Newman projectionshowing the lowest P.E. conformation (sighting down this same bond). c. To draw a Newman projection in the lowest P.E. conformation, the following rule of thumbusually applies: Place the largest group on the front carbon anti to the largest group on theback carbon. Is your answer to the previous question consistent with this rule of thumb?
Fill in the blanks: cis-1,3-Dimethylcyclohexane has two different chair conformations: one withboth methyl groups in __________ positions and one with both methyl groups in ____________ positions.
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Draw a chair conformation of this molecule with (a) all CH3 groups in axial positions and (b) all CH3 groups in equatorial positions.
There are three distinct chair conformations for cyclohexylcyclohexane. (a) Draw all three and (b) determine which one is the most stable. Cyclohexylcyclohexane
Draw the “chair twist" of the following molecules. Label the more stable conformation. Br •CH3 OH Draw planar models of the above molecules. Draw both chair conformation of the following molecule, and identify the most stable form. Me Me ....Et Me
Predict the most stable conformation for each of the following molecules. Brietly explain why your conformer is the more stable conformation. a) b) OH OH
Solve this problem
a) Draw the chair conformations of 1, 4 – ditertbutyl cyclohexane and all of its ring flips.b) Determine the most stable and least stable conformations. Explain your answer.
Consider the following chair conformation of bromocyclohexane: H H H Br H H H (a) Identify whether the bromine atom occupies an axial position or an equatorial position in the conformation above. (b) Draw a bond-line drawing (skeletal structure) of this chair conformation (without Newman projections). (c) Draw a bond-line drawing of the other chair conformation (after a ring flip).
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