11. Given the reaction below, answer the following questions: Br + KI acetone A a) Based on the equation above and knowing that an excess of potassium iodide is used, would you expect this reaction to be favorable? Please explain. b) This is a reaction commonly employed in organic chemistry and takes several hours of heating the mixture at reflux for the reaction to go to completion. During the course of the reaction a crystalline precipitate forms. What is the precipitate? Why does this provide the driving force for the reaction? c) In general this reaction is not used in practice to convert optically active secondary alkyl bromides to optically active alkyl iodides because the alkyl iodide products tend to lose optical activity if the reactions are run too long or if too much potassium iodide is used. Please explain.

Chemistry: The Molecular Science
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ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
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Chapter14: Acids And Bases
Section14.1: Bronsted-lowry Acids And Bases
Problem 14.2CE: Using Le Chatelier’s Principle Use Le Chatelier’s principle (← Sec. 12-6b) to explain why the...
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11. Given the reaction below, answer the following questions:
Br +
KI
acetone
A
a) Based on the equation above and knowing that an excess of potassium iodide is used, would
you expect this reaction to be favorable? Please explain.
b) This is a reaction commonly employed in organic chemistry and takes several hours of heating
the mixture at reflux for the reaction to go to completion. During the course of the reaction a
crystalline precipitate forms. What is the precipitate?
Why does this provide the
driving force for the reaction?
c) In general this reaction is not used in practice to convert optically active secondary alkyl
bromides to optically active alkyl iodides because the alkyl iodide products tend to lose optical
activity if the reactions are run too long or if too much potassium iodide is used. Please
explain.
Transcribed Image Text:11. Given the reaction below, answer the following questions: Br + KI acetone A a) Based on the equation above and knowing that an excess of potassium iodide is used, would you expect this reaction to be favorable? Please explain. b) This is a reaction commonly employed in organic chemistry and takes several hours of heating the mixture at reflux for the reaction to go to completion. During the course of the reaction a crystalline precipitate forms. What is the precipitate? Why does this provide the driving force for the reaction? c) In general this reaction is not used in practice to convert optically active secondary alkyl bromides to optically active alkyl iodides because the alkyl iodide products tend to lose optical activity if the reactions are run too long or if too much potassium iodide is used. Please explain.
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