Consider 2-methylpropane (isobutane). Sighting along the C2-C1 bond: (a) Draw a Newman projection of the most stable conformation. (b) Draw a Newman projection of the least stable conformation. (c) Make a graph of energy versus angle of rotation around the C2-C1 bond. (d) Since an H H eclipsing interaction costs 4.0 kJ/mol and an H CH3 eclip ing interaction costs 6.0 kl/mol, assign relative values to the maxima and minima in your graph.
Consider 2-methylpropane (isobutane). Sighting along the C2-C1 bond: (a) Draw a Newman projection of the most stable conformation. (b) Draw a Newman projection of the least stable conformation. (c) Make a graph of energy versus angle of rotation around the C2-C1 bond. (d) Since an H H eclipsing interaction costs 4.0 kJ/mol and an H CH3 eclip ing interaction costs 6.0 kl/mol, assign relative values to the maxima and minima in your graph.
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter2: Alkanes And Cycloalkanes
Section2.5: Conformations Of Alkanes And Cycloalkanes
Problem 2.9P: Following is a chair conformation of cyclohexane with the carbon atoms numbered 1 through 6. (a)...
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