12. Arrange the following in order of (i) increasing acidity, (ii) increasing pka : (b) CC13CO₂H (d) CH3CH2SH (a) CH3CO₂H (c) CH3CH2OH 13. What would be the major products of the reactions of (i) butanoic acid and (ii) benzoic acid with each of the following: (a) SOC12, Et3N (c) (CH3)2CHOH/H* / heat (b) LiAlH4/THF then acidic work-up (d) NaOH

12. Arrange the following in order of (i) increasing acidity, (ii) increasing pka : (b) CC13CO₂H (d) CH3CH2SH (a) CH3CO₂H (c) CH3CH2OH 13. What would be the major products of the reactions of (i) butanoic acid and (ii) benzoic acid with each of the following: (a) SOC12, Et3N (c) (CH3)2CHOH/H* / heat (b) LiAlH4/THF then acidic work-up (d) NaOH

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

(i) Compare the biological activities of morphine and apomorphine (structures shown below). (ii) Provide a detailed mechanism (curved-arrow formalism) for the conversion of morphine to apomorphine under acid-catalyzed conditions. но. HO. но HO" morphine apomorphine
Please don't provide handwriting solution
Describe a synthetic plan with justification of the sequence of reactions you would take to complete the synthesis of 1. Suggest reagents
2- Arrange the following compounds in the approximate order of their basicity toward 5% hydrochloric acid solution: Diphenylamine, benzylamine, 4-methylaniline, benzamide
A solution of the following three compounds in ether is extracted first with aqueous HCl, secondly with aqueous NaHCO3. Where will each of the three compounds reside after the procedure: the NaHCO3 extract, the HCl extract, or the ether layer? Please explain with the help of pKa numbers. (image of compounds attached)
For the following molecules, suggest two retrosynthesis pathways with their synthetic equivalents. (a) (b) Ph (c) (d) HO HO ОН HO 'NH2 OH
(ii) Suggest a synthesis of ketone 6 from (E)-3,4-(dimethoxy) cinnamic acid 9. You can assume that any other reagents will be made available to you. MeO MeO 9 CO₂H steps MeO MeO 6
8
Please don't provide handwriting solution
Give the molecular structures of reagent or products for the following chemical reactions: (1) KMNO4, HO, heat PC15 (i) LIAIH(O-t-Bu)3, Et,O, -78°C H;O (A) (B) (C) (а) (ii) H2O OH SOCII, NaCN (i) DIBAL-H, Hexane (E) (F) HCN (b) (ii) H20 (G) (i) DIBAL-H, Hexane HO. (i) LIAIH4 (H) (I) (c) (ii) H2O (ii) H2O
how "Ethylphenylketone, (C,H,COCH₂CH₂)" could be synthesized from each of the following: (1) Benzene (2) Benzonitrile, C.HSCEN (3) Benzaldehyde
[6] Give a plausible catalytic cycle for the conversion of benzyl iodide and carbon monoxide to phenylacetic acid using NH4* [IRh(CO)2] as the catalyst.