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Predict the products of the following reactions. Indicate regioselectivity where relevant. (The aromatic ring is inert to all the indicated reagents.) H2/Pd (a) ? Br2 (b) HBr (c) Styrene KMNO4 (d) NaOH, H2O 7. Show the alkyne and alkyl halide from which the following products can be obtained. Where two routes look feasible, list both. CH3 CH3CHCH2CH2C=CH CH3 CH3CHC=CCH3 (a) (b) CH3CH2CH2C=CCH3 (c) B. Give IUPAC names for the following compounds: (a) CI, „Br (b) CH3 (c) „NH2 CH2CH,ĊHCH3 Br (d) CI CH3 (e) CH2CH3 (f) CH3 CH3 O2N' `NO2 H3C *CH3 Show the mechanism of the reaction of benzene with nitric acid and sulfuric acid to yield nitrobenzene. 10. What products would you expect to obtain from the reaction of benzene with the following reagents?

Predict the products of the following reactions. Indicate regioselectivity where relevant. (The aromatic ring is inert to all the indicated reagents.) H2/Pd (a) ? Br2 (b) HBr (c) Styrene KMNO4 (d) NaOH, H2O 7. Show the alkyne and alkyl halide from which the following products can be obtained. Where two routes look feasible, list both. CH3 CH3CHCH2CH2C=CH CH3 CH3CHC=CCH3 (a) (b) CH3CH2CH2C=CCH3 (c) B. Give IUPAC names for the following compounds: (a) CI, „Br (b) CH3 (c) „NH2 CH2CH,ĊHCH3 Br (d) CI CH3 (e) CH2CH3 (f) CH3 CH3 O2N' `NO2 H3C *CH3 Show the mechanism of the reaction of benzene with nitric acid and sulfuric acid to yield nitrobenzene. 10. What products would you expect to obtain from the reaction of benzene with the following reagents?

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Predict the products of the following reactions. Indicate regioselectivity where relevant. (The aromatic ring is inert to all the indicated reagents.) (a) H/Pd ? Br2 C. (b) ? HBr (c) ? Styrene KMNO4 (d) NaOH, H2O 7. Show the alkyne and alkyl halide from which the following products can be obtained. Where two routes look feasible, list both. CH3 CH3 CH3CHCH2CH2C=CH (a) (b) CH3CH2CH2C=CCH3 (c) CH3CHC=CCH3 8. Give IUPAC names for the following compounds: (a) Cl. CH3 NH2 Br (b) (c) CH2CH2CHCH3 Br (d) CI CH3 (e) CH2CH3 (f) CH3 „CH3 O2N `NO2 H3C *CH3 9. Show the mechanism of the reaction of benzene with nitric acid and sulfuric acid to yield nitrobenzene. 10. What products would you expect to obtain from the reaction of benzene with the following reagents? (a) (CH3)3CCI, AICI3 (b) CH3CH2COCI, AIC13 11. See Fundamentals P167 for Figure 5.6 Use Figure 5.6 to rank the compounds in each of the following groups in order of their reactivity toward electrophilic aromatic substitution: (a) Nitrobenzene, phenol (hydroxybenzene), toluene (b) Phenol, benzene, chlorobenzene, benzoic acid (c) Benzene, bromobenzene, benzaldehyde, aniline (aminobenzene)
Transcribed Image Text:Predict the products of the following reactions. Indicate regioselectivity where relevant. (The aromatic ring is inert to all the indicated reagents.) (a) H/Pd ? Br2 C. (b) ? HBr (c) ? Styrene KMNO4 (d) NaOH, H2O 7. Show the alkyne and alkyl halide from which the following products can be obtained. Where two routes look feasible, list both. CH3 CH3 CH3CHCH2CH2C=CH (a) (b) CH3CH2CH2C=CCH3 (c) CH3CHC=CCH3 8. Give IUPAC names for the following compounds: (a) Cl. CH3 NH2 Br (b) (c) CH2CH2CHCH3 Br (d) CI CH3 (e) CH2CH3 (f) CH3 „CH3 O2N `NO2 H3C *CH3 9. Show the mechanism of the reaction of benzene with nitric acid and sulfuric acid to yield nitrobenzene. 10. What products would you expect to obtain from the reaction of benzene with the following reagents? (a) (CH3)3CCI, AICI3 (b) CH3CH2COCI, AIC13 11. See Fundamentals P167 for Figure 5.6 Use Figure 5.6 to rank the compounds in each of the following groups in order of their reactivity toward electrophilic aromatic substitution: (a) Nitrobenzene, phenol (hydroxybenzene), toluene (b) Phenol, benzene, chlorobenzene, benzoic acid (c) Benzene, bromobenzene, benzaldehyde, aniline (aminobenzene)
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