Predict the products of the following reactions. Indicate regioselectivity where relevant. (The aromatic ring is inert to all the indicated reagents.) H2/Pd (a) ? Br2 (b) HBr (c) Styrene KMNO4 (d) NaOH, H2O 7. Show the alkyne and alkyl halide from which the following products can be obtained. Where two routes look feasible, list both. CH3 CH3CHCH2CH2C=CH CH3 CH3CHC=CCH3 (a) (b) CH3CH2CH2C=CCH3 (c) B. Give IUPAC names for the following compounds: (a) CI, „Br (b) CH3 (c) „NH2 CH2CH,ĊHCH3 Br (d) CI CH3 (e) CH2CH3 (f) CH3 CH3 O2N' `NO2 H3C *CH3 Show the mechanism of the reaction of benzene with nitric acid and sulfuric acid to yield nitrobenzene. 10. What products would you expect to obtain from the reaction of benzene with the following reagents?

Predict the products of the following reactions. Indicate regioselectivity where relevant. (The aromatic ring is inert to all the indicated reagents.) H2/Pd (a) ? Br2 (b) HBr (c) Styrene KMNO4 (d) NaOH, H2O 7. Show the alkyne and alkyl halide from which the following products can be obtained. Where two routes look feasible, list both. CH3 CH3CHCH2CH2C=CH CH3 CH3CHC=CCH3 (a) (b) CH3CH2CH2C=CCH3 (c) B. Give IUPAC names for the following compounds: (a) CI, „Br (b) CH3 (c) „NH2 CH2CH,ĊHCH3 Br (d) CI CH3 (e) CH2CH3 (f) CH3 CH3 O2N' `NO2 H3C *CH3 Show the mechanism of the reaction of benzene with nitric acid and sulfuric acid to yield nitrobenzene. 10. What products would you expect to obtain from the reaction of benzene with the following reagents?

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Concept explainers

Diol

In chemistry there are so many chemical compounds that have a hydroxyl group but a chemical compound having two hydroxyl groups (-OH) is termed as a diol. It also implies the presence of two alcohols whereas polyols contain two or more than two hydroxyl groups (-OH). Glycol or 1,2-diol is an aliphatic diol that has two alcohol groups on adjacent carbon atoms. In industries, the most commonly used diol is ethylene glycol.

Question

Predict the products of the following reactions. Indicate regioselectivity
where relevant. (The aromatic ring is inert to all the indicated reagents.)
(a)
H/Pd
?
Br2
C.
(b)
?
HBr
(c)
?
Styrene
KMNO4
(d)
NaOH, H2O
7.
Show the alkyne and alkyl halide from which the following products can be
obtained. Where two routes look feasible, list both.
CH3
CH3
CH3CHCH2CH2C=CH
(a)
(b) CH3CH2CH2C=CCH3
(c)
CH3CHC=CCH3
8.
Give IUPAC names for the following compounds:
(a) Cl.
CH3
NH2
Br
(b)
(c)
CH2CH2CHCH3
Br
(d) CI
CH3
(e)
CH2CH3
(f)
CH3
„CH3
O2N
`NO2
H3C
*CH3
9.
Show the mechanism of the reaction of benzene with nitric acid and sulfuric
acid to yield nitrobenzene.
10.
What products would you expect to obtain from the reaction of benzene with the
following reagents?
(a) (CH3)3CCI, AICI3
(b) CH3CH2COCI, AIC13
11. See Fundamentals P167 for Figure 5.6
Use Figure 5.6 to rank the compounds in each of the following groups in order
of their reactivity toward electrophilic aromatic substitution:
(a) Nitrobenzene, phenol (hydroxybenzene), toluene
(b) Phenol, benzene, chlorobenzene, benzoic acid
(c) Benzene, bromobenzene, benzaldehyde, aniline (aminobenzene)

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