Stoichiometric Characterization Lab Report

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Oct 30, 2023

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Stoichiometric Characterization of Compounds and Mixtures 26 January 2023 Tryston Schmitt CHEM 1310 Laboratory, Section A28 Data and Results Table 1. Measurement of H 2 O 2 :Na 2 CO 3 molar ratio in sodium percarbonate. Table 2. Measurement of the mass percentage of NaCl in a mixture of NaCl and NaNO 3 .
Figure 1. Mass percentages of sodium, chlorine, nitrogen, and oxygen in the studied mixture. Discussion In the first part of the experiment, many separate reactions take place. First, sodium percarbonate is dissolved in water to break it into its specific ions: Na 2 CO 3 · n H 2 O 2 ( s ) → 2 N a + ( aq ) + CO 3 2 ( aq ) + n H 2 O 2 ( aq ); next, iodide is added to the solution which reacts with aqueous hydrogen peroxide: H 2 O 2 ( aq ) + 2 H + ( aq ) + 3 I ( aq ) → 2 H 2 O( l ) + I 3 ( aq ); finally, sodium thiosulfate solution is added to the mixture to determine how much triiodide was produced in the previous reaction: I 3 ( aq ) + 2 S 2 O 3 2 ( aq ) → 3 I ( aq ) + S 4 O 6 2 ( aq ). In the second part of the experiment, one main reaction occurs. In an aqueous solution of sodium chloride (NaCl) and sodium nitrate (NaNO 3 ), silver reacts with the chlorine ions to form silver chloride precipitate: Ag + ( aq ) + Cl ( aq ) → AgCl ( s ). In addition to this main reaction, once all of the chlorine anions are consumed, excess silver reacts with chromate ions in a potassium chromate indicator (K 2 CrO 4 ) to make a red tint in the solution: 2 Ag + ( aq ) + CrO 4 2 ( aq ) → A g 2 CrO 4 ( s ), this tint is indicative of the chloride fully reacted. In experiment one, the end goal is to find the ratio of sodium carbonate to hydrogen peroxide. First, we find the mols of thiosulfate added to the solution; because the solution was (0.1 mol/L) we can simply multiply the number of mL added to the solution by this ratio and divide by 1000 due to the conversion between mL and L. In the case of my data, I added 0.000277 mols S 2 O 3 2 . After we ve obtained this value, we can
work backwards through stoichiometric calculations to find the mols of hydrogen peroxide in the solution. The ratio between S 2 O 3 2 and I 3 is 2:1, therefore there are 0.0001385 mols of I 3 . The ratio between I 3 and H 2 O 2 is 1:1, therefore there are 0.0001385 mols of H 2 O 2 as well. Now that we have the number of mols of hydrogen peroxide, we can convert back into grams in order to find the mass of the Na 2 CO 3 . The molar mass of H 2 O 2 is 33.96 grams, so by multiplying by that value, we find that there are 0.004703 grams of H 2 O 2 in the solution ( 33 .96 ????? ??? ???) × ( 0 .0001385 ????) = 0 .004703 ????? . Subtracting this value from the mass of the sodium percarbonate mass recorded in the very beginning of the experiment (0.027 grams) tells us that the solution contains 0.02229 grams of Na 2 CO 3 . Now, we can convert this value into mols by dividing by the molar mass of Na 2 CO 3 (82.998 grams) (0 .02229 grams Na 2 CO 3 ) (82 .998 grams per mol ) = 0.0002686 mol Na 2 CO 3 . Now, we have the number of moles of sodium carbonate and hydrogen peroxide, we can use these to write the chemical equation: (Na 2 CO 3 ) 0.0002686 (H 2 O 2 ) 0.0001385 , we can then find the ratio between the two (n) by dividing both mol numbers by the smallest number of mols. 0 .0002686 ?𝑜? Na 2 CO 3 0 .0001385 = 1.935. This is the ratio between the two compounds. In experiment two, we want to find the mass percentage of sodium chloride in a sodium chloride + sodium nitrate solid (NaCl+ NaNO 3 ). First, we find the mass of the silver nitrate solution added to the sodium solution; this mass can be found by subtracting the mass of the solution in the Erlenmeyer flask before silver nitrate was added from the mass after the silver nitrate was added: ???? ?? 𝐴?? ? 3 ?????𝑖?? = ( ???? ????? ???𝑖?𝑖?? ?? 𝐴?? ? 3 ?????𝑖??) (???? ?????? ???𝑖?𝑖?? ?? 𝐴?? ? 3 ?????𝑖?? ) For me, this value was 5.823 grams. Then, by multiplying this value by the percent by weight of silver nitrate in the solution (1.7% W/W), we get the mass of silver nitrate added. ( 5 .823 ????? 𝐴?? ? 3 ?????𝑖??) × 0 .017 = (0 .09899 ????? 𝐴?? ? 3 ) . Now, this value can be converted into mols by dividing by the molar mass of silver nitrate (169.374 grams): 0 .09899 𝑔?𝑎?? 𝐴𝑔? ? 3 169 .374 𝑔?𝑎?? /?𝑜? = 0.0005827 mols AgN O 3 . Through the stoichiometric ratios present in the chemical equation in which AgN O 3 reacts with NaCl, we find that the ratio of AgN O 3 to NaCl is 1:1, therefore, there are 0.0005827mols of NaCl present in the sample. Multiplying this number of mols by the molar mass of NaCl (58.44 grams), gives the mass of sodium chloride present in the sample. (0 .0005827 ??? ??𝐶? ) × (58 .44 ????? /??? ) = 0.03405 grams of NaCl. Now, by dividing this amount by the mass of sodium chloride + sodium nitrate solid, we can find the mass percentage of sodium chloride in the mixture: 0 .03405 𝑔?𝑎?? ?𝑎𝐶? 0 .05 𝑔?𝑎?? ?𝑖𝑥???𝑒 × 100% = 68 .10% ??𝐶? ?𝑦 ???? .
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