Quiz_ F21 Final exam

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University of California, Irvine *

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13000

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Chemistry

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Feb 20, 2024

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F21 Final exam ! This is a preview of the published version of the quiz Started: Dec 7 at 10:31am Quiz Instructions You can use any of the resources provided through this course (homework solutions, lecture notes, book, etc.) and any others you like (e.g. internet search). But you CANNOT use interactive resources of any kind, including speaking to or interacting with a person live (not in person, not on discord, not on a question site). Only static (non-interactive) resources are allowed. Respond to the first question of the exam certifying that you are taking the exam in compliance with these guidelines and those of the UCI academic honesty policy. Use the values for constants, EM spectrum, and electronegativities in the following files when answering exam problems: ENGR1A_F21_midterm1_const-EM-PT.pdf (https://canvas.eee.uci.edu/courses/38739/files/16169292/download?download_frd=1) Midterm 2 electronegativity PT.pdf (https://canvas.eee.uci.edu/courses/38739/files/16370306/download?download_frd=1) Post private notes to me on Ed Discussion or call me at 949-824-1194 if you have issues during the exam. 0 pts Question 1 YES NO I certify that I am taking this exam in accordance with the UCI academic honesty policy linked on the course syllabus, and according to the instructor’s guidelines, including not consulting other people or interactive resources during the exam. .
1 pts Question 2 cesium iodine aluminum zirconium gallium The highest energy electron in the ground state of an atom has quantum numbers n = 4, l = 1, m = 0, m = +1/2. This atom could be: l s 1 pts Question 3 CaBr Ca Br Ca Br CaBr CaBr What would be the expected chemical formula of the ionic compound containing only Ca and Br? 3 2 4 2 2 1 pts Question 4
In Cd Sn Sb Ag All of the following atoms could have ground state electron configurations of [Kr] 4d except 10 3+ 2+ 4+ 4+ + 1 pts Question 5 As < Rb < Br < Se < Sr As < Se < Br < Rb < Sr As < Sr < Se < Br < Rb Rb < Br < Sr < Se < As Sr < Rb < Br < Se < As Arrange the following ions in order from smallest to largest ionic radius: As , Rb , Br , Se , Sr 3- + - 2- 2+ 3- + - 2- 2+ 3- 2- - + 2+ 3- 2+ 2- - + + - 2+ 2- 3- 2+ + - 2- 3- 1 pts Question 6 For the bonds C—S, C—F, and C—O, polarity of the bond increases in the following order:
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C—O < C—F < C—S C—S < C—F < C—O C—S < C—O < C—F C—O < C—S < C—F C—F < C—S < C—O 1 pts Question 7 NO BrO FNO NO ClO Select all of the following molecules with Lewis dot structures that DO NOT satisfy the octet rule. Note: look carefully at the molecular charge for the molecular ions in the following list. - 2 2 - 2 1 pts Question 8 None of these What is the formal charge on each N atom (in any order) in the Lewis structure of the N anion? 3 -
-1, +1, -1 +2, -1, 0 0, -1, 0 -2, +1, 0 1 pts Question 9 2- 1- 2+ 1+ 3+ What is the oxidation state of a Co atom with the following electron energy diagram: 1 pts Question 10
None of the above 0.43 and 0.47 0.49 and 0.41 0.24 and 0.66 0.79 and 0.11 Hypothetical element X has three naturally occurring isotopes ( X, X, and X) and has an atomic mass of 24.31 amu. The masses of X, X, and X are 23.9850, 24.9858, and 25.9826 amu, respectively. If the fractional abundance of X is 0.1000, what are the fractional abundances of X and X? 24 25 26 24 25 26 25 24 26 1 pts Question 11 Sb Sb Ge Si S Select all of the following ions that are expected to be paramagnetic in their ground state. 3+ 3- 2+ 4+ 2+ 1 pts Question 12
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Tetrahedral Linear Seesaw Trigonal bipyramidal Octahedral What is the molecular structure of IBr ? 2 - 1 pts Question 13 PH SO FeCl ClO NI Which of these is the most ionic compound of those listed? 3 2 3 2 3 1 pts Question 14 Which of the following is the most stable Lewis structure of ClO ? 3 -
1 pts Question 15 1.33 What is the N—O bond order in the Lewis structure of NO ? 2 +
3 1 1.5 2 1 pts Question 16 -2 0 -1 +1 None of the above What is the formal charge on the central O atom in the Lewis structure of O ? 3 1 pts Question 17 Which is the most stable Lewis structure of ICN?
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1 pts Question 18 [Ne]3s 3p [Ne]3s 3p [Ne]3s 3p [Ne]3s [Ne]3s 3p Consider the following ground state electron configurations. Which corresponds to the atom with the greatest first ionization energy according to periodic table trends? 2 3 2 1 2 5 2 2 4 1 pts Question 19 Sn Cd Which element has the electron configuration [Kr] 5s 4d in its 1+ oxidation state? 2 10
In Ag Sb 1 pts Question 20 Trigonal bipyramidal Trigonal pyramidal Seesaw Trigonal planar T-shaped What is the molecular geometry of BrCl ? 3 1 pts Question 21 SO bond angle > SO bond angle More information is needed to predict relative bond angles SO bond angle = SO bond angle SO bond angle < SO bond angle What are the relative bond angles of O—S—O bonds in SO and SO ? 4 2- 2 2 4 2- 2 4 2- 2 4 2-
1 pts Question 22 Te Si Se Sr Cl Which of the following elements has the highest expected electronegativity based on periodic table trends? 1 pts Question 23 Because its wavelength is too short Because its frequency is too low. Because of the uncertainty principle Because its kinetic energy is too small Because its wavelength is too long The wavelike properties of a baseball thrown at 1 m · s cannot be observed because of which of the following? -1 1 pts Question 24
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2.48 x 10 m · s 1.43 x 10 m · s 8.24 x 10 m · s 1.21 x 10 m · s 4.03 x 10 m · s What is the speed of a Li atom (mass = 1.15 x 10 kg) that has a de Broglie wavelength of 1.43 x 10 m? -26 -12 -5 -1 -12 -1 -20 -1 19 -1 4 -1 1 pts Question 25 5s 4p 5d 5p 4d An electron in a hydrogen atom is excited to a state with quantum numbers n = 5, l = 1, m = 0, m = -1/2. To which subshell is the electron excited? l s 1 pts Question 26
7 6 3 2 4 How many valence electrons does the neutral atom represented in the following energy level diagram have? 1 pts Question 27 V Ti Cr Ni Ca Select all of the following atoms that have 28 neutrons 51 48 52 58 40
1 pts Question 28 1.9 x 10 J 2.6 x 10 J 5.2 x 10 J 6.1 x 10 J 1.9 x 10 J How much energy is in 1 mole of 640 nm photons? 5 -16 -43 -19 42 1 pts Question 29 3.45 x 10 m 1.17 x 10 m 2.90 x 10 m 3.45 x 10 m 1.54 x 10 m Assuming electron orbital energies in Be obey the Bohr model, what wavelength of light is emitted by the relaxation of an electron from the n = 4 to the n = 3 state? 3+ -4 -7 3 -9 -6 1 pts Question 30
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46.2 g 11.6 g 4.60 g 54.5 g 23.1 g The molar mass of a Cl atom is 35.45 g · mol . What is the mass of 0.652 moles of Cl? -1 1 pts Question 31 N N N N N Use molecular orbital theory to predict which molecule has the greatest bond order: 2 + 2 2- 2 2 - 2 2+ 1 pts Question 32
Saving... sp sp sp d sp sp d What is the orbital hybridization of the central C atom in methylamine, CH NH ? 3 2 2 3 2 3 3 1 pts Question 33 C H (hint: H CCH ) C H (hint: H CCH ) C H (hint: HCCH) Use Lewis dot structures to determine which of the following molecules has the shortest C--C bond length.C 2 4 2 2 2 6 3 3 2 2 Submit Quiz